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Methyl 4-chloro-3-oxo-butanoate

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Methyl 4-chloro-3-oxo-butanoate Basic information

Product Name:
Methyl 4-chloro-3-oxo-butanoate
Synonyms:
  • Methyl omega-chloroacetoacetate
  • Acetoacetic acid, 4-chloro-, methyl ester
  • Butanoicacid,4-chloro-3-oxo-,methylester
  • gamma-Chloroacetoacetic acid, methyl ester
  • Methyl gamma-chloroacetoacetate
  • 4-chloro-3-oxo-butanoicacimethylester
  • 4-chloro-acetoaceticacimethylester
  • Oxiracetam Impurity 20
CAS:
32807-28-6
MF:
C5H7ClO3
MW:
150.56
EINECS:
251-230-5
Product Categories:
  • Aliphatics
  • Intermediates & Fine Chemicals
  • Organic acids
  • C2 to C5
  • Carbonyl Compounds
  • Pharmaceuticals
  • Halogen compounds
  • Esters
Mol File:
32807-28-6.mol
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Methyl 4-chloro-3-oxo-butanoate Chemical Properties

Melting point:
14-16 °C
Boiling point:
85 °C/4 mmHg (lit.)
Density 
1.305 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.456(lit.)
Flash point:
217 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Sparingly), Ethyl Acetate (Slightly)
form 
Liquid
pka
9.54±0.46(Predicted)
Specific Gravity
1.28
color 
Colorless
Water Solubility 
71 g/L (20 ºC)
BRN 
1759939
Stability:
Moisture Sensitive
InChIKey
HFLMYYLFSNEOOT-UHFFFAOYSA-N
LogP
1.010 (est)
CAS DataBase Reference
32807-28-6(CAS DataBase Reference)
NIST Chemistry Reference
Butanoic acid, 4-chloro-3-oxo-, methyl ester(32807-28-6)
EPA Substance Registry System
Methyl 4-chloroacetoacetate (32807-28-6)
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Safety Information

Hazard Codes 
T
Risk Statements 
25-34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 2810 6.1/PG 2
WGK Germany 
3
RTECS 
AK5115000
19
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29183000

MSDS

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Methyl 4-chloro-3-oxo-butanoate Usage And Synthesis

Chemical Properties

Methyl 4-chloro-3-oxo-butanoate is clear slightly yellow to yellow-orange liquid

Uses

γ-Chloroacetic acid derivative with acute toxicity used in the preparation of insecticides.

Uses

Reacts with symmetric allylic diacetates or dicarbonates in the presence of a palladium catalyst to give dihyrofurans.

Methyl 4-chloro-3-oxo-butanoate Preparation Products And Raw materials

Preparation Products

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