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TRIS(4-CHLOROPHENYL)PHOSPHINE

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TRIS(4-CHLOROPHENYL)PHOSPHINE Basic information

Product Name:
TRIS(4-CHLOROPHENYL)PHOSPHINE
Synonyms:
  • Tri(p-chlorophenyl)phosphine,99%
  • TRIS(P-CHLOROPHENYL)PHOSPHINE
  • TRIS(4-CHLOROPHENYL)PHOSPHINE
  • TRI(P-CHLOROPHENYL)PHOSPHINE
  • TRI(4-CHLOROPHENYL)PHOSPHINE
  • Phosphine, tris(4-chlorophenyl)-
  • Phosphine, tris(p-chlorophenyl)-
  • 1,1-dimethyl-3-(5-nitro-1,2-benzothiazol-3-yl)urea
CAS:
1159-54-2
MF:
C18H12Cl3P
MW:
365.62
EINECS:
214-596-7
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
  • Ligand
  • Basic Phosphine LigandsCatalysis and Inorganic Chemistry
  • Catalysis and Inorganic Chemistry
  • organophosphorus ligand
  • Cross-Coupling
  • Phosphine Ligands
  • Phosphorus Compounds
Mol File:
1159-54-2.mol
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TRIS(4-CHLOROPHENYL)PHOSPHINE Chemical Properties

Melting point:
100-103 °C (lit.)
Boiling point:
427.6±40.0 °C(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
crystal
color 
white
Sensitive 
Air Sensitive
BRN 
751458
CAS DataBase Reference
1159-54-2(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
RIDADR 
3278
WGK Germany 
3
TSCA 
No
PackingGroup 
III
HS Code 
29310099

MSDS

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TRIS(4-CHLOROPHENYL)PHOSPHINE Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

Catalyst for:

  • Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes
  • Solvent-free Heck reactions

Cocatalyst in:
  • Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents
  • Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes
  • Rhodium-catalyzed hydrogenation reactions
  • Platinum-catalyzed allylation reactions

TRIS(4-CHLOROPHENYL)PHOSPHINESupplier

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