(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine
(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine Basic information
- Product Name:
- (1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine
- Synonyms:
-
- (1R,2R)-(-)-N1,N2-Dimethylcyclohexane-1,2-diamine 95%
- (1S,2S)-N1,N2-dimethylcyclohexane-1,2-diamine
- (1R,2R)-(-)-1,2-BIS(METHYLAMINO)CYCLOHEXANE
- (1R,2R)-1,2-BIS(METHYLAMINO)CYCLOHEXANE
- (1R,2R)-(-)-N,N'-DIMETHYLCYCLOHEXANE-1,2-DIAMINE
- (1R,2R)-N,N'-DIMETHYL-1,2-CYCLOHEXANEDIAMINE
- (1R,2R)-DIAMINOMETHYLCYCLOHEXANE
- trans-1,2-Bis(methylamino)cyclohexane, (R,R)-(-)-N,Nμ-Dimethyl-1,2-diaminocyclohexane
- CAS:
- 68737-65-5
- MF:
- C8H18N2
- MW:
- 142.24
- Product Categories:
-
- Chiral Building Blocks
- e.e. / Absolute Configuration Determination (NMR)
- Amines and Anilines
- Amines (Chiral)
- Enantiomer Excess & Absolute Configuration Determination
- Synthetic Organic Chemistry
- chiral
- Analytical Chemistry
- Chiral Nitrogen
- DACH&Trost Series
- Mol File:
- 68737-65-5.mol
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(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine Chemical Properties
- Melting point:
- 39-44 °C
- alpha
- -145 º (c=4.47 in chloroform)
- Boiling point:
- 249.85°C (rough estimate)
- Density
- 0.902
- refractive index
- -140 ° (C=4, CHCl3)
- Flash point:
- 74 °C
- storage temp.
- 2-8°C
- form
- Low Melting Solid
- pka
- 11.04±0.40(Predicted)
- color
- White to light yellow
- optical activity
- [α]/D -145±5°, c = 4.47 in chloroform
- InChIKey
- JRHPOFJADXHYBR-HTQZYQBOSA-N
- CAS DataBase Reference
- 68737-65-5(CAS DataBase Reference)
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Safety Information
- Hazard Codes
- C
- Risk Statements
- 34-22
- Safety Statements
- 45-36/37/39-25-26
- RIDADR
- 3259
- WGK Germany
- 3
- HazardClass
- 8
- PackingGroup
- Ⅱ
- HS Code
- 29213000
MSDS
- Language:English Provider:ACROS
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(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine Usage And Synthesis
Chemical Properties
white to light yellow crystal powde
Uses
(R,R)-(?)-N,N′-Dimethyl-1,2-cyclohexanediamine can be used:
- As a ligand in the preparation of 4H-benzo[f]imidazo[1,4]diazepin-6-one through multi-component Ullmann coupling reaction.
- In one of the key synthetic steps for the preparation of tricyclic γ-secretase modulators.
- To prepare chiral fluorous diamino-diol proligand, which is used in the synthesis of zirconium metal complexes applicable as catalysts in 1-hexene polymerization.
General Description
(R,R)-(-)-N,N′-Dimethyl-1,2-cyclohexanediamine is a N,N′-dimethylated derivative of enantiopure 1,2-diaminocyclohexane. It can be formed during the hydrolysis of (R3a,R7a)-1,3-(dimethyl)-2-phenyl-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3,2-benzodiazaphosphole 2-oxide using HCl-methanol.
(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamineSupplier
Chengdu Forest Science and Technology Development Co., Ltd. Gold
- Tel
- 18030648795 18030648795
- sales@cdforestchem.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
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Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
- market03@meryer.com
TCI (Shanghai) Development Co., Ltd.
- Tel
- 021-67121386
- Sales-CN@TCIchemicals.com
Beijing HwrkChemical Technology Co., Ltd
- Tel
- 010-89508211 18501085097
- sales.bj@hwrkchemical.com
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(1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine(68737-65-5)Related Product Information
- Dimethyl ether
- 1,2-Diaminocyclohexane
- (+/-)-trans-1,2-Diaminocyclohexane
- Dimethyl phthalate
- N,N-Dimethylformamide
- Dimethyl fumarate
- Dimethyl sebacate
- Dimethyl sulfoxide
- 1,2-Cyclohexanedione
- 1,2-Cyclohexylenedinitrilotetraacetic acid
- Hexamethylenediamine
- Dimethyl carbonate
- ETHANE
- trans-1,4-Diaminocyclohexane
- N,N'-Dimethyl-1,2-cyclohexanediamine
- (1S,2S)-N,N'-Dimethyl-1,2-cyclohexanediamine,(S,S)-(+)-N,Nμ-Dimethyl-1,2-cyclohexanediamine
- CDTA
- (+)-U-50488 HYDROCHLORIDE