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2-Pentylpyridine

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2-Pentylpyridine Basic information

Product Name:
2-Pentylpyridine
Synonyms:
  • 1-(2-PYRIDYL)PENTANE
  • 2-amylpyridine
  • 2-pentyl-pyridin
  • FEMA NUMBER 3383
  • FEMA 3383
  • 2-N-AMYLPYRIDINE
  • 2-PENTYLPYRIDINE
  • 2-N-PENTYLPYRIDINE
CAS:
2294-76-0
MF:
C10H15N
MW:
149.23
EINECS:
218-937-0
Mol File:
2294-76-0.mol
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2-Pentylpyridine Chemical Properties

Boiling point:
102-107 °C (lit.)
Density 
0.897 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.488(lit.)
FEMA 
3383 | 2-PENTYLPYRIDINE
Flash point:
175 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
clear liquid
pka
6.01±0.10(Predicted)
Specific Gravity
0.902
color 
Colorless to Light yellow
Odor
at 0.10 % in propylene glycol. fatty tallow green pepper mushroom herbal
Odor Type
fatty
JECFA Number
1313
BRN 
2772
LogP
3.31
CAS DataBase Reference
2294-76-0(CAS DataBase Reference)
NIST Chemistry Reference
Pyridine, 2-pentyl-(2294-76-0)
EPA Substance Registry System
2-Pentylpyridine (2294-76-0)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29333990

MSDS

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2-Pentylpyridine Usage And Synthesis

Chemical Properties

2-Pentylpyridine has a tallowy-like odor.

Occurrence

Reported as occurring in shallow-fried beef and as a steam-volatile component in roasted Spanish peanut. Also reported found in bell pepper, black sesame seeds, roast turkey, fried chicken, fried beef, cooked beef, mutton, lamb fat, roasted filberts, toasted oats and coriander seed.

Definition

ChEBI: 2-Pentylpyridine is a member of pyridines.

Preparation

By alkylation of 2-pycollyl lithium; by hydrogenation of 2-pentenyl pyridine.

Aroma threshold values

Detection: 0.6 ppb. Aroma characteristics at 0.1%: strong fresh green vegetative, peppery, mushroom, herbal and oily.

Taste threshold values

Taste characteristics at 1 ppm: green pepper vegetative, mushroom-like, musty, oily, meaty and MSG-like.

Purification Methods

Dry it with NaOH for several days, then distil it from CaO under reduced pressure, taking the middle fraction and redistilling it. The picrate has m 72-72.8o (from EtOH). [Beilstein 20 III/IV 2835.] 3-n-Pentylpyridine, purified as the 2-isomer, has b 110-112o/20mm, 224-226o/748mm, and the picrate has m 79.5-80o(from EtOH). [Beilstein 20 III/IV 2835.]

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