dipotassium tetrachloroplatinate
dipotassium tetrachloroplatinate Basic information
- Product Name:
- dipotassium tetrachloroplatinate
- Synonyms:
-
- PLATINOUS POTASSIUM CHLORIDE
- PLATINUM(II) DIPOTASSIUM TETRACHLORIDE
- PLATINUM(II) POTASSIUM CHLORIDE
- PLATINUM (OUS) POTASSIUM CHLORIDE
- PLATINUM POTASSIUM CHLORIDE
- POTASSIUM CHLOROPLATINITE
- POTASSIUM PLATINUM TETRACHLORIDE
- POTASSIUM PLATINOUS CHLORIDE
- CAS:
- 10025-99-7
- MF:
- Cl4KPt-
- MW:
- 375.98
- EINECS:
- 233-050-9
- Product Categories:
-
- chemical reaction,pharm,electronic,materials
- halometallate salt
- Materials Science
- Metal and Ceramic Science
- Potassium Salts
- Salts
- Inorganics
- Mol File:
- 10025-99-7.mol
dipotassium tetrachloroplatinate Chemical Properties
- Melting point:
- 250°C
- Density
- 3.38 g/mL at 25 °C(lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- soluble in Water
- form
- Crystals or Crystalline Powder
- Specific Gravity
- 3.38
- color
- Red-brown
- Water Solubility
- 10 g/L (20 ºC)
- Sensitive
- Hygroscopic
- Merck
- 14,7682
- Exposure limits
- ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3 - Stability:
- Stable. Incompatible with acids, strong oxidizing agents.
- InChIKey
- RVRDLMCWUILSAH-UHFFFAOYSA-J
- CAS DataBase Reference
- 10025-99-7(CAS DataBase Reference)
- EPA Substance Registry System
- Platinate(2-), tetrachloro-, dipotassium, (SP-4-1)- (10025-99-7)
Safety Information
- Hazard Codes
- T,Xi
- Risk Statements
- 25-38-41-42/43
- Safety Statements
- 22-26-36/37/39-45
- RIDADR
- UN 3288 6.1/PG 3
- WGK Germany
- 1
- RTECS
- TP1850000
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- Ⅲ
- HS Code
- 28439000
MSDS
- Language:English Provider:dipotassium tetrachloroplatinate
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
dipotassium tetrachloroplatinate Usage And Synthesis
Chemical Properties
Red/Brown, Tetragonal Crystals
Uses
Potassium tetrachloroplatinate solution is used in the preparation of platinum (Pt) nanoparticles. Ligands like ammonia or triphenyl phosphine can able to replace the chloride ligands to afford various derivatives. The replacement by ammonia results in the preparation of cisplatin, which is used in the cancer treatment. Further, it is used as catalyst in the hydroarylation reaction.
Uses
In photography, in acid toning baths.
General Description
Potassium tetrachloroplatinate(II) is a ruby red crystalline solid and can be prepared by reacting potassium hexachloroplatinate (IV) with cuprous chloride.
Flammability and Explosibility
Non flammable
Safety Profile
Human poison by ingestion. Poison experimentally by intraperitoneal route. Corrosive to human skin by intradermal route. Mutation data reported. Human systemic effects: eosinophha, gastritis, renal function tests depressed. When heated to decomposition it emits toxic fumes of Cland K2O. Used as a catalyst for hydroformulations, photocatalysts, and dissociation of water. See also PLATINUM COMPOUNDS.
Purification Methods
It forms crystals from aqueous 0.75M HCl (20mL/g) between 100o and 0o. Wash them with ice-cold water and dry.
dipotassium tetrachloroplatinate Preparation Products And Raw materials
Preparation Products
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