Basic information Safety Supplier Related

Potassium chloropalladite

Basic information Safety Supplier Related

Potassium chloropalladite Basic information

Product Name:
Potassium chloropalladite
Synonyms:
  • PotassiuM tetrachloropalladate(II) 99.99% trace Metals basis
  • PALLADOUS POTASSIUM CHLORIDE
  • PALLADIUM(II) POTASSIUM CHLORIDE
  • POTASSIUM TETRACHLOROPALLADATE
  • POTASSIUM TETRACHLOROPALLADATE(II)
  • POTASSIUM PALLADIUM(II) CHLORIDE
  • POTASSIUM CHLOROPALLADITE
  • Dipotassium tetrachloropalladate
CAS:
10025-98-6
MF:
Cl4K2Pd
MW:
326.43
EINECS:
233-049-3
Product Categories:
  • chemical reaction,pharm,electronic,materials
  • Materials Science
  • halometallate salt
  • Metal and Ceramic Science
  • Potassium Salts
  • Salts
Mol File:
10025-98-6.mol
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Potassium chloropalladite Chemical Properties

Melting point:
105 °C (dec.)(lit.)
Density 
2.67 g/mL at 25 °C(lit.)
storage temp. 
Inert atmosphere,Room Temperature
form 
Crystals or Crystalline Powder
Specific Gravity
2.67
color 
Red-brown
Water Solubility 
SOLUBLE
Sensitive 
Hygroscopic
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
LGCKLDWLSVFMGL-UHFFFAOYSA-J
CAS DataBase Reference
10025-98-6(CAS DataBase Reference)
EPA Substance Registry System
Palladate(2-), tetrachloro-, potassium (1:2), (SP-4-1)- (10025-98-6)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38-36/38
Safety Statements 
26-36-37/39
WGK Germany 
3
RTECS 
TT4100000
TSCA 
Yes
HS Code 
28429080

MSDS

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Potassium chloropalladite Usage And Synthesis

Chemical Properties

solid

Uses

Potassium tetrachloropalladate(II) is widely used as a reagent and as a source of palladium chloride to make other palladium complexes and palladium nanoparticles. It finds an application in the synthesis of semiconducting metal-containing polymers. It also reacts with bis(dithiolates) to form metal-bis(dithiolates), which is used in bar code material, laser Q-switch materials, optical CD recording media and superconductivity.

Uses

Potassium chloropalladite can be used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1

Purification Methods

All operations should be carried out in an efficient fume cupboard. Cyanide is very POISONOUS. Dissolve the complex (ca 5g)in a solution of KCN (4g) in H2O (75mL) with warming and stirring, and evaporate hot till crystals appear. Cool, filter off the crystals and wash them with a few drops of cold H2O. Further concentration of the mother liquors provides more crystals. The complex is recrystallised from H2O as the colourless trihydrate. It effloresces in dry air and dehydrates at 100o to the monohydrate. The anhydrous salt is obtained by heating at 200o, but at higher temperatures it decomposes to (CN)2, Pd and KCN. [Bigelow Inorg Synth II 245 1946.]

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