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Chloroformamidine hydrochloride

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Chloroformamidine hydrochloride Basic information

Product Name:
Chloroformamidine hydrochloride
Synonyms:
  • CHLOROFORMAMIDINE HYDROCHLORIDE
  • Chloroformamide hydrochloride
  • chloroformamidinium chloride
  • ChloroformamidineHCl
  • CARBAMIMIDIC ACID CHLORIDE HYDROCHLORIDE
  • Carbamimidic chloride hydrochloride
  • CarbaMiMidic chloride, Monohydrochloride
  • Chloroformamidine hydrochloride 98%
CAS:
29671-92-9
MF:
CH4Cl2N2
MW:
114.96
EINECS:
249-765-4
Mol File:
29671-92-9.mol
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Chloroformamidine hydrochloride Chemical Properties

Melting point:
180°C(lit.)
Density 
1.5592 (rough estimate)
refractive index 
1.6300 (estimate)
storage temp. 
Inert atmosphere,Room Temperature
form 
powder to crystal
color 
White to Almost white
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Safety Information

HazardClass 
IRRITANT
HS Code 
2925290090
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Chloroformamidine hydrochloride Usage And Synthesis

Chemical Properties

White crystalline powder

Reactions

In efforts to optimize a manufacturing process for an internal development compound, a clean, efficient approach to guanidine synthesis using chloroformamidine hydrochloride was identified. The successful application of this chemistry to a variety of pyridines, anilines, and heterocyclic compounds highlights its use as an improved, alternative guanylation method for this often challenging set of aromatic amines.[1]

Materials Uses

An interfacial molecular linker, chloroformamidine hydrochloride (CFA), is introduced to modify the properties of electron transport layers (ETLs) and modulate the interaction between the ETL and perovskite (PVK) layer via coordination/electrostatic coupling. It is found that the CFA molecular linker can passivate the oxygen vacancies/interfacial defects of SnO2 and construct an improved energetic alignment between the ETL and PVK layer. Moreover, unencapsulated PSCs based on CFA-modified SnO2 (CFA@SnO2) ETLs show enhanced thermal and moisture stability compared with PSCs without CFA modification.[2]

References

[1] IAN ARMITAGE. The Use of Chloroformamidine Hydrochloride as a Reagent for the Synthesis of Guanidines from Electron Deficient Aromatic Amines[J]. Journal of Heterocyclic Chemistry, 2015, 54 1: 728-734. DOI:10.1002/jhet.2567.
[2] LI H, FU P, LU R, et al. Chloroformamidine hydrochloride as a molecular linker towards efficient and stable perovskite solar cells?[J]. Journal of Materials Chemistry C, 2023, 15: 5039-5044. DOI:10.1039/D3TC00637A.

Chloroformamidine hydrochloride Preparation Products And Raw materials

Raw materials

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