Basic information Safety Supplier Related
ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Esters >  Methyl ester compound >  METHYL ALPHA-BROMOPHENYLACETATE

METHYL ALPHA-BROMOPHENYLACETATE

Basic information Safety Supplier Related

METHYL ALPHA-BROMOPHENYLACETATE Basic information

Product Name:
METHYL ALPHA-BROMOPHENYLACETATE
Synonyms:
  • -(1H-1,2,4-triazol-1-ylmethyl)-4-pyrimidineethanol-d3
  • -altropyranoside
  • Methyl alpha-bromobenzeneacetate
  • Methyl bromophenylacetate
  • Methyl2-bromo-2-phenylacetate
  • Methyla-bromo-a-phenylacetate
  • Methyla-bromobenzeneacetate
  • ALPHA-BROMOPHENYLACETIC ACID METHYL ESTER
CAS:
3042-81-7
MF:
C9H9BrO2
MW:
229.07
EINECS:
608-480-9
Product Categories:
  • Building Blocks
  • C8 to C9
  • Aromatic Phenylacetic Acids and Derivatives
  • Carbonyl Compounds
  • Chemical Synthesis
  • Organic Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • Esters
Mol File:
3042-81-7.mol
More
Less

METHYL ALPHA-BROMOPHENYLACETATE Chemical Properties

Boiling point:
113 °C3 mm Hg(lit.)
Density 
1.46 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.554
Flash point:
>230 °F
storage temp. 
2-8°C
form 
clear liquid
color 
Colorless to Light orange to Yellow
BRN 
1102743
InChIKey
NHFBYYMNJUMVOT-UHFFFAOYSA-N
More
Less

Safety Information

Hazard Codes 
C
Risk Statements 
36/37/38-34
Safety Statements 
26-36/39-45-36/37/39
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
II
HS Code 
29163990

MSDS

More
Less

METHYL ALPHA-BROMOPHENYLACETATE Usage And Synthesis

Chemical Properties

Light yellow to yellow liquid

Uses

Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.

Synthesis Reference(s)

Tetrahedron, 42, p. 2275, 1986 DOI: 10.1016/S0040-4020(01)90607-6

General Description

Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.

METHYL ALPHA-BROMOPHENYLACETATESupplier

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Email
market03@meryer.com
Alfa Aesar
Tel
400-6106006
Email
saleschina@alfa-asia.com
Dr. J. Pharmachem (India)
Tel
+91 20 24332987
Email
info@jpharmachem.com
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Email
Sales-CN@TCIchemicals.com
More
Less

METHYL ALPHA-BROMOPHENYLACETATE(3042-81-7)Related Product Information