METHYL ALPHA-BROMOPHENYLACETATE

Product Name: METHYL ALPHA-BROMOPHENYLACETATE
CAS No.: 3042-81-7
Chemical Name: METHYL ALPHA-BROMOPHENYLACETATE
Synonyms: Methyl α-altropyranoside;(2RS,3RS)-α-L-Lyxopyranoside;Methyl α-broMo acid;-Bromophenylacetate;-Cyclopentylmandelate;4-(Methoxy-d3)-αMethylbromophenylacetate;Methyl bromophenylacetate
CBNumber: CB4266950
Molecular Formula: C9H9BrO2
Formula Weight: 229.07
MOL File: 3042-81-7.mol

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METHYL ALPHA-BROMOPHENYLACETATE Property

Boiling point:: 113 °C3 mm Hg(lit.)
Density: 1.46 g/mL at 20 °C(lit.)
refractive index: n20/D 1.554
Flash point:: >230 °F
storage temp.: 2-8°C
form: clear liquid
color: Colorless to Light orange to Yellow
BRN: 1102743
InChIKey: NHFBYYMNJUMVOT-UHFFFAOYSA-N

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Safety

Hazard Codes: C
Risk Statements: 36/37/38-34
Safety Statements: 26-36/39-45-36/37/39
RIDADR: UN 3265 8/PG 2
WGK Germany: 3
HazardClass: 8
PackingGroup: II
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 365270
Product name: Methyl α-bromophenylacetate
Purity: 97%
Packaging: 5g
Price: $61.4
Updated: 2024/03/01

TCI Chemical

Product number: M2038
Product name: Methyl α-Bromophenylacetate
Purity: >98.0%(GC)
Packaging: 5g
Price: $70
Updated: 2024/03/01

TCI Chemical

Product number: M2038
Product name: Methyl α-Bromophenylacetate
Purity: >98.0%(GC)
Packaging: 25g
Price: $196
Updated: 2024/03/01

TRC

Product number: M294940
Product name: Methyl α-bromophenylacetate
Packaging: 25g
Price: $230
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0007769
Product name: METHYL ALPHA-BROMOPHENYL ACETATE
Purity: 95.00%
Packaging: 1G
Price: $619.7
Updated: 2021/12/16

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METHYL ALPHA-BROMOPHENYLACETATE Chemical Properties,Usage,Production

Chemical Properties

Light yellow to yellow liquid

Uses

Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.

Synthesis Reference(s)

Tetrahedron, 42, p. 2275, 1986 DOI: 10.1016/S0040-4020(01)90607-6

General Description

Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.

METHYL ALPHA-BROMOPHENYLACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL ALPHA-BROMOPHENYLACETATE Suppliers

Americas 1 China 79 Europe 1 Germany 2 India 3 Japan 1 Switzerland 2 United Kingdom 6 United States 14 Global 109

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
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Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
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Alfa Aesar

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Dr. J. Pharmachem (India)

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TCI (Shanghai) Development Co., Ltd.

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Beijing HwrkChemical Technology Co., Ltd

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Energy Chemical

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Fax: 021-58436166
Email: sales8178@energy-chemical.com
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Shanghai Longsheng chemical Co.,Ltd.

Tel: 021-58099652-8005 13585536065
Fax: 021-58099609
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Country: China
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Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
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Country: China
ProdList: 42958
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Chemsky（shanghai）International Co.,Ltd.

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 32321
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View Lastest Price from METHYL ALPHA-BROMOPHENYLACETATE manufacturers

Career Henan Chemical Co

Product: METHYL ALPHA-BROMOPHENYLACETATE 3042-81-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-12-30

3042-81-7, METHYL ALPHA-BROMOPHENYLACETATERelated Search:

Methyl Bromopyruvate 2'-BROMO-3,4-DICHLOROPHENYLACETIC ACID METHYL ESTER (3-BROMOPHENYL)ACETIC ACID METHYL ESTER METHYL 2-(2-BROMOPHENYL)ACETATE METHYL ALPHA-BROMOPHENYLACETATE ALPHA-BROMO-3-CHLOROBENZENEACETIC ACID ETHYL ESTER METHYL ALPHA-BROMO-2-CHLOROPHENYLACETATE Ethyl α-bromophenylacetate ETHYL 2-BROMO-(4-BROMOPHENYL)ACETATE Methyl 4-bromophenylacetate 2-Bromo-2-phenylacetic acid Methyl phenylacetate METHYL 2-BROMO-2-(4'-CYANOPHENYL)ACETATE BROMO-(4-FLUORO-PHENYL)-ACETIC ACID ETHYL ESTER METHYL BROMO(4-FLUOROPHENYL)ACETATE A-BROMO-2,4-DICHLOROBENZENEACETIC ACID ETHYL ESTER METHYL 2-BROMO-2-(2-NITROPHENYL) ACETATE ALPHA-BROMO-1-NAPHTHALENEACETIC ACID ETHYL ESTER

-(1H-1,2,4-triazol-1-ylmethyl)-4-pyrimidineethanol-d3

-altropyranoside

Methyl alpha-bromobenzeneacetate

Methyl bromophenylacetate

Methyl2-bromo-2-phenylacetate

Methyla-bromo-a-phenylacetate

Methyla-bromobenzeneacetate

ALPHA-BROMOPHENYLACETIC ACID METHYL ESTER

METHYL (+/-)-ALPHA-BROMOPHENYLACETATE

METHYL ALPHA-BROMOPHENYLACETATE

METHYL A-BROMOPHENYLACETATE

Methylbromophenylacetate

-Cyclopentylmandelate

-L-Idopyranosiduronic Acid Sodium Salt

-L-Lyxopyranoside

-(1H-1,2,4-triazol-1-ylmethyl)-4-pyrimidineethanol

-(2,4-Difluorophenyl)-5-fluoro-&beta

(2RS,3RS)-&alpha

4-(Methoxy-d3)-&alpha

S)-benzeneethanamine Hydrochloride

Methyl α-broMo acid

Methyl alpha-bromophenylacetate 97%

-Bromophenylacetate

Methyl &alpha

(R,S)-Bromo-phenyl-aceticacidmethylester

a-Bromophenylaceticacidmethylester

Benzeneaceticacid,a-bromo-,methylester

Benzeneaceticacid,α-bromo-,methylester

Methyl alpha-bromo-alpha-phenylacetate

MethylDL-bromophenylacetate

Methylα-bromophenylacetate

R,S-Bromo-phenyl-aceticacidmethylester

Methyl ɑ-bromophenylacetate, 97%

METHYL (+/-)-ALPHA-BROMOPHENYLACETATE, 9 7%

2-BROMO-2-PHENYLACETIC ACID METHYL ESTER

(±)-α-bromophenylacetic acid methyl ester

à-bromophenylacetic acid methyl ester

methyl à-bromophenylacetate

Phenylbromoacetic acid methyl ester

α-Bromobenzeneacetic acid methyl ester

Methylα-Bromophenylacetate&gt

Benzeneacetic acid, α-bromo-, methyl ester

Methyl α-Bromophenylacetate

α- Bromo-Phenyl Acetic Acid Methyl Ester

3042-81-7

C6H5CHBrCOOCH3

C6H5CHBrCO2CH3

C8 to C9

Carbonyl Compounds

Building Blocks

Esters

Organic Building Blocks

Building Blocks

C8 to C9

Carbonyl Compounds

Chemical Synthesis

Organic Building Blocks

Aromatic Phenylacetic Acids and Derivatives