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METHYL ALPHA-BROMOPHENYLACETATE

Product Name
METHYL ALPHA-BROMOPHENYLACETATE
CAS No.
3042-81-7
Chemical Name
METHYL ALPHA-BROMOPHENYLACETATE
Synonyms
Methyl α-altropyranoside;(2RS,3RS)-α-L-Lyxopyranoside;Methyl α-broMo acid;-Bromophenylacetate;-Cyclopentylmandelate;4-(Methoxy-d3)-αMethylbromophenylacetate;Methyl bromophenylacetate
CBNumber
CB4266950
Molecular Formula
C9H9BrO2
Formula Weight
229.07
MOL File
3042-81-7.mol
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METHYL ALPHA-BROMOPHENYLACETATE Property

Boiling point:
113 °C3 mm Hg(lit.)
Density 
1.46 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.554
Flash point:
>230 °F
storage temp. 
2-8°C
form 
clear liquid
color 
Colorless to Light orange to Yellow
BRN 
1102743
InChIKey
NHFBYYMNJUMVOT-UHFFFAOYSA-N
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Safety

Hazard Codes 
C
Risk Statements 
36/37/38-34
Safety Statements 
26-36/39-45-36/37/39
RIDADR 
UN 3265 8/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
II
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
365270
Product name
Methyl α-bromophenylacetate
Purity
97%
Packaging
5g
Price
$63.3
Updated
2025/07/31
TCI Chemical
Product number
M2038
Product name
Methyl α-Bromophenylacetate
Purity
>98.0%(GC)
Packaging
5g
Price
$70
Updated
2025/07/31
TCI Chemical
Product number
M2038
Product name
Methyl α-Bromophenylacetate
Purity
>98.0%(GC)
Packaging
25g
Price
$196
Updated
2025/07/31
TRC
Product number
M294940
Product name
Methyl α-bromophenylacetate
Packaging
25g
Price
$230
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0007769
Product name
METHYL ALPHA-BROMOPHENYL ACETATE
Purity
95.00%
Packaging
1G
Price
$619.7
Updated
2021/12/16
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METHYL ALPHA-BROMOPHENYLACETATE Chemical Properties,Usage,Production

Chemical Properties

Light yellow to yellow liquid

Uses

Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.

Synthesis Reference(s)

Tetrahedron, 42, p. 2275, 1986 DOI: 10.1016/S0040-4020(01)90607-6

General Description

Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.

METHYL ALPHA-BROMOPHENYLACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYL ALPHA-BROMOPHENYLACETATE manufacturers

Career Henan Chemical Co
Product
METHYL ALPHA-BROMOPHENYLACETATE 3042-81-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-12-30

3042-81-7, METHYL ALPHA-BROMOPHENYLACETATERelated Search:

Methyl Bromopyruvate 2'-BROMO-3,4-DICHLOROPHENYLACETIC ACID METHYL ESTER (3-BROMOPHENYL)ACETIC ACID METHYL ESTER METHYL 2-(2-BROMOPHENYL)ACETATE METHYL ALPHA-BROMOPHENYLACETATE ALPHA-BROMO-3-CHLOROBENZENEACETIC ACID ETHYL ESTER METHYL ALPHA-BROMO-2-CHLOROPHENYLACETATE Ethyl α-bromophenylacetate ETHYL 2-BROMO-(4-BROMOPHENYL)ACETATE Methyl 4-bromophenylacetate 2-Bromo-2-phenylacetic acid Methyl phenylacetate METHYL 2-BROMO-2-(4'-CYANOPHENYL)ACETATE BROMO-(4-FLUORO-PHENYL)-ACETIC ACID ETHYL ESTER METHYL BROMO(4-FLUOROPHENYL)ACETATE A-BROMO-2,4-DICHLOROBENZENEACETIC ACID ETHYL ESTER METHYL 2-BROMO-2-(2-NITROPHENYL) ACETATE ALPHA-BROMO-1-NAPHTHALENEACETIC ACID ETHYL ESTER

  • -(1H-1,2,4-triazol-1-ylmethyl)-4-pyrimidineethanol-d3
  • -altropyranoside
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  • Methyl2-bromo-2-phenylacetate
  • Methyla-bromo-a-phenylacetate
  • Methyla-bromobenzeneacetate
  • ALPHA-BROMOPHENYLACETIC ACID METHYL ESTER
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  • Methylbromophenylacetate
  • -Cyclopentylmandelate
  • -L-Idopyranosiduronic Acid Sodium Salt
  • -L-Lyxopyranoside
  • -(1H-1,2,4-triazol-1-ylmethyl)-4-pyrimidineethanol
  • -(2,4-Difluorophenyl)-5-fluoro-&beta
  • (2RS,3RS)-&alpha
  • 4-(Methoxy-d3)-&alpha
  • S)-benzeneethanamine Hydrochloride
  • Methyl α-broMo acid
  • Methyl alpha-bromophenylacetate 97%
  • -Bromophenylacetate
  • Methyl &alpha
  • (R,S)-Bromo-phenyl-aceticacidmethylester
  • a-Bromophenylaceticacidmethylester
  • Benzeneaceticacid,a-bromo-,methylester
  • Benzeneaceticacid,α-bromo-,methylester
  • Methyl alpha-bromo-alpha-phenylacetate
  • MethylDL-bromophenylacetate
  • Methylα-bromophenylacetate
  • R,S-Bromo-phenyl-aceticacidmethylester
  • Methyl ɑ-bromophenylacetate, 97%
  • METHYL (+/-)-ALPHA-BROMOPHENYLACETATE, 9 7%
  • 2-BROMO-2-PHENYLACETIC ACID METHYL ESTER
  • (±)-α-bromophenylacetic acid methyl ester
  • à-bromophenylacetic acid methyl ester
  • methyl à-bromophenylacetate
  • Phenylbromoacetic acid methyl ester
  • α-Bromobenzeneacetic acid methyl ester
  • Methylα-Bromophenylacetate&gt
  • Benzeneacetic acid, α-bromo-, methyl ester
  • Methyl α-Bromophenylacetate
  • α- Bromo-Phenyl Acetic Acid Methyl Ester
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  • 3042-81-7
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