Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4
Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4 Basic information
- Product Name:
- Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4
- Synonyms:
-
- Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4
- Tetrakis[(R)-(-)-[(1R)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodium(II)
- Rh2(R-BTPCP)4
- CAS:
- 1345974-62-0
- MF:
- C88H64Br4O8Rh2
- MW:
- 1774.9
- Mol File:
- 1345974-62-0.mol
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Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4 Chemical Properties
- Melting point:
- >300°C
- form
- solid
- color
- green
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Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4 Usage And Synthesis
Reaction
- Chiral catalyst used for the enantioselective formation of cyclopropanes from the reaction of aryls with styryl diazoacetates.
- Chiral catalyst used for the asymmetric synthesis of bicyclo[1.1.0]butane rings via the rhodium-catalyzed decomposition of 2-diazo-5-arylpent-4-enoates.
- Rhodium-Catalyzed [4+3] Cycloaddition between Vinyldiazoacetates and Dienes.
Uses
Rh catalyst developed by the Davies lab used for enantioselective cyclopropanations and C-H funcionalization under low catalyst loadings.
Tetrakis[(R)-(-)-[(1R)-1-(4-broMophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodiuM(II) Rh2(R-BTPCP)4Supplier
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