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4-Biphenylcarbonyl chloride

Basic information Safety Supplier Related

4-Biphenylcarbonyl chloride Basic information

Product Name:
4-Biphenylcarbonyl chloride
Synonyms:
  • Biphenyl-4-carbonylchloride98%
  • Biphenyl-4-carboxyl chloride
  • P-PHENYLBENZOYL CHLORIDE
  • 4-PHENYLBENZOYL CHLORIDE
  • 4-BIPHENYLCARBONYL CHLORIDE
  • 4-BIPHENYLCARBONYL CHLORIDE CRYSTALLINE
  • Biphenyl-4-carbonyl chloride 98%
  • BIPHENYL-4-CARBONYL CHLORIDE
CAS:
14002-51-8
MF:
C13H9ClO
MW:
216.66
EINECS:
237-804-8
Product Categories:
  • Biphenyl derivatives
  • Absolute Configuration Determination (Exciton Chirality CD Method)
  • Analytical Chemistry
  • Enantiomer Excess & Absolute Configuration Determination
  • Exciton Chirality CD Method (for Hydroxyl Groups)
Mol File:
14002-51-8.mol
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4-Biphenylcarbonyl chloride Chemical Properties

Melting point:
110-112 °C (lit.)
Boiling point:
160 °C / 2mmHg
Density 
1.1459 (rough estimate)
refractive index 
1.5260 (estimate)
storage temp. 
Inert atmosphere,Room Temperature
form 
Fine Crystalline Powder
color 
White to yellow
Water Solubility 
HYDROLYSIS
Sensitive 
Moisture Sensitive/Lachrymatory
BRN 
472842
InChIKey
JPVUWCPKMYXOKW-UHFFFAOYSA-N
CAS DataBase Reference
14002-51-8(CAS DataBase Reference)
EPA Substance Registry System
[1,1'-Biphenyl]-4-carbonyl chloride (14002-51-8)
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Safety Information

Hazard Codes 
C
Risk Statements 
14-34
Safety Statements 
26-36/37/39-43-45-25
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
21-10
Hazard Note 
Corrosive/Lachrymatory/Moisture Sensitive
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29163990

MSDS

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4-Biphenylcarbonyl chloride Usage And Synthesis

Chemical Properties

4-Biphenylcarbonyl chloride is white to yellow fine crystalline powder

Uses

Biphenyl-4-carbonyl chloride was used in the preparation of a novel thiourea compound, N-(6-methyl pyridin-2-yl-carbamothioyl)biphenyl-4-carboxamide. It was also used in the preparation of 5-CF3-oxazole analog, 2-{4-[2-(2-biphenyl-4-yl-5-trifluoromethyl-oxazol-4-yl)-ethoxy]-phenoxy}-2-methyl-propionic acid.

Purification Methods

Dissolve the carbonyl chloride in a large volume of pet ether (10 x, b 50-70o), filter it through a short column of neutral alumina, evaporate to dryness in vacuo and recrystallise it from pet ether (b 60-80o). [Beilstein 9 IV 2480.] LACHRYMATORY.

4-Biphenylcarbonyl chloride Preparation Products And Raw materials

Raw materials

4-Biphenylcarbonyl chlorideSupplier

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