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BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE

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BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE Basic information

Product Name:
BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE
Synonyms:
  • potassium bis(4-(trifluoromethyl)phenyl)phosphide
  • DI-(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE
  • BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE
  • Bis(4-trifluoromethylphenyl)phosphine,98%
  • Bis(4-trifluoromethylphenyl)phosphine 97%
  • Phosphine, bis[4-(trifluoromethyl)phenyl]-
CAS:
99665-68-6
MF:
C14H9F6P
MW:
322.19
Mol File:
99665-68-6.mol
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BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE Chemical Properties

Boiling point:
291.4±40.0 °C(Predicted)
Density 
1.317 g/mL at 25 °C
refractive index 
n20/D1.512
form 
liquid
InChI
1S/C14H9F6P/c15-13(16,17)9-1-5-11(6-2-9)21-12-7-3-10(4-8-12)14(18,19)20/h1-8,21H
InChIKey
LLJITAAISCMRAR-UHFFFAOYSA-N
SMILES
FC(F)(F)c1ccc(Pc2ccc(cc2)C(F)(F)F)cc1
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Safety Information

Hazard Codes 
T
Risk Statements 
25-37-41
Safety Statements 
26-39-45
RIDADR 
UN 2810 6.1 / PGIII
WGK Germany 
WGK 3
Storage Class
6.1D - Non-combustible acute toxic Cat.3
toxic hazardous materials or hazardous materials causing chronic effects
Hazard Classifications
Acute Tox. 3 Oral
Aquatic Chronic 4
Eye Dam. 1
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BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE Usage And Synthesis

Uses

Reactant for:

  • Preparation of iron(II) chiral diimine diphosphine complexes as catalysts for asymmetric transfer hydrogenation of ketones
  • Enantioselective decarboxylative allylation and ring-closing metathesis

reaction suitability

reagent type: ligand

BIS(4-TRIFLUOROMETHYLPHENYL)PHOSPHINESupplier

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