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ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Phosphine ligand >  (R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE

(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE

Basic information Uses Safety Supplier Related

(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Basic information

Product Name:
(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
Synonyms:
  • (R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE
  • (R)-1-{(S)-2-[Bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocenyl}ethyldicyclo
  • (R)-(-)-1-{(S)-2-[Bis(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine,min.97%
  • (r,r)-1-[1-(dicyclohexylphosphino)ethyl]-2-[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene (acc to cas)
  • (R)-1-{(S)-2-[Bis(4-Methoxy-3,5-diMeth
  • (R)-(-)-1-{(S)-2-[Bis(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine, min. 97%
  • (R)-(-)-1-{(S)-2-[Bis(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocenyl}
    ethyldicyclohexylphosphine, min. 97%
  • (R)-(-)-1-{(S)-2-[Bis(3,5-diMethyl-4-Methoxyphenyl)phosphino]ferrocenyl}ethyldicyclohexylphosphine
CAS:
360048-63-1
MF:
C42H50FeO2P2
MW:
704.65
Product Categories:
  • Chiral Phosphine
  • Ferrocene Series
  • organophosphine ligand
  • Josiphos Series
Mol File:
360048-63-1.mol
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(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Chemical Properties

alpha 
-270° ±10° (c 0.5, CHCl3)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
orange
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Safety Information

WGK Germany 
3
HS Code 
29319090
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(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE Usage And Synthesis

Uses

  1. Homogeneous chiral nickel-catalyzed asymmetric hydrogenation of substituted aromatic α-aminoketone hydrochlorides through dynamic kinetic resolution.
  2. Pd/Josiphos-catalyzed enantioselective α-arylation of silyl ketene acetals.
  3. Ligand used in the cobalt-catalyzed asymmetric addition of silylacetylenes to 1,1-disubstitued allenes.

Chemical Properties

(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINE is Orange powder

General Description

sold in collaboration with Solvias AG

(R)-(-)-1-[(S)-2-(DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINO)FERROCENYL]ETHYLDICYCLOHEXYLPHOSPHINESupplier

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