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Ferrous ammonium sulfate hexahydrate

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Ferrous ammonium sulfate hexahydrate Basic information

Product Name:
Ferrous ammonium sulfate hexahydrate
Synonyms:
  • FERROUS AMMONIUM SULFATE HEXAHYDRATE*SIG MAULTRA
  • AMMONIUM IRON(II) SULFATE HEXAHYDRATE, 9 9.997%
  • AMMONIUM IRON(II) SULFATE HEXAHYDRATE, 9 9%, A.C.S. REAGENT
  • AMMONIUM IRON(II) SULFATE HEXAHYDRATE, REAGENTPLUS TM, >= 99%
  • AMMONIUM IRON(II) SULFATE-6-HYDRATE EXTR A PURE
  • AMMONIUM IRON(II) SULFATE-6-HYDRATE R. G., REAG. ISO, RE
  • AmmoniumIron(II)SulfateHexahydrateReagentAcs(Crystals)
  • FerrousAmmmoniumSulfate,Hexahydrate
CAS:
7783-85-9
MF:
FeH7NO5S
MW:
188.96
EINECS:
616-518-0
Product Categories:
  • metal sulfate
Mol File:
7783-85-9.mol
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Ferrous ammonium sulfate hexahydrate Chemical Properties

Melting point:
100 °C (dec.)(lit.)
Density 
1,864 g/cm3
vapor density 
> 1 (vs air)
storage temp. 
Store at +15°C to +25°C.
solubility 
H2O: 0.5 M at 20 °C, clear, faintly yellow-green
form 
Solid
Specific Gravity
1.864
color 
Pale green
Odor
Odorless
PH
2.5-4.0 (25℃, 0.5M in H2O)
Water Solubility 
269 g/L (20 ºC)
Sensitive 
Air & Light Sensitive
Merck 
14,521
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
Stability:
Stable. Incompatible with sulfuric acid.
CAS DataBase Reference
7783-85-9(CAS DataBase Reference)
EPA Substance Registry System
Ferrous ammonium sulfate hexahydrate (7783-85-9)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
1
RTECS 
BR6500000
8-10-23
TSCA 
Yes
HS Code 
28429090
Toxicity
LD50 orally in Rabbit: 3250 mg/kg

MSDS

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Ferrous ammonium sulfate hexahydrate Usage And Synthesis

Chemical Properties

Ferrous ammonium sulfate is a pale green or blue-green solid (powder or lumpy crystals).

Chemical Properties

Ferrous ammonium sulfate hexahydrate is pale blue-green solid

Uses

Ammonium iron(II) sulfate hydrate is widely utilized in analytical chemistry for titration purposes since it is affected lesser by oxygen in the air than iron(II) sulpahte. It is employed to measure high doses of gamma rays by using Fricke's dosemeter. It is involved in a variety of other applications from nanomaterials to general redox reactions. It is used in the medical field as an antianemic agent for treatment of iron deficiency.

Uses

Used as analytical standard.

Definition

ChEBI: A hydrate that is the hexahydrate form of ferrous ammonium sulfate. Acts as an iron ion donor for building Fe-S clusters in vitro.

Potential Exposure

Ferrous ammonium sulfate hexahydrate is used in photography, analytical chemistry and in dosimeters.

Purification Methods

A solution in warm water (0.67g/mL) is cooled rapidly to 0o, and the resulting light bluish-green monoclinic crystals are filtered at the pump, washed with cold distilled water and pressed between sheets of filter paper to dry it. The solubility at 25o is 0.36g/mL. It separates as an almost white powder when a saturated aqueous solution is diluted with EtOH.

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