N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Basic information
- Product Name:
- N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
- Synonyms:
-
- N,N-bis[(1R)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine
- N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
- BIPOL-A1(S), (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(S)-1-phenylethyl]phosphoramidite
- N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
- N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
- 1,1'-Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite
- Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite
- Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1S)-1-phenylethyl]-
- CAS:
- 376355-58-7
- MF:
- C28H26NO2P
- MW:
- 439.49
- Product Categories:
-
- phosphine-amine ligand
- Chiral Phosphine
- CPN
- Mol File:
- 376355-58-7.mol
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N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Chemical Properties
- Melting point:
- 99-102 °C
- Boiling point:
- 578.4±53.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- -0.31±0.20(Predicted)
- form
- Powder
- color
- white
- optical activity
- [α]/D -250±10°, c = 1 in toluene
- Sensitive
- moisture sensitive
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N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Usage And Synthesis
Reaction
- Ligand for the copper catalyzed, highly regioselective substitution reactions of a wide variety of aromatic substituted allylic halides to form branched chiral products from diverse Grignard reagents.
- Ligand for the copper catalyzed, highly enantioselective conjugate addition of diethylzinc to eneones and nitro olefins.
- Ligand for the nickel catalyzed, highly enantioselective hydrovinylation of alkenes.
- Ligand for the rhodium catalyzed, highly enantioselective hydroformylation of vinylarenes.
- Ligand for gold catalyzed asymmetric Intramolecular hydroamination of allenes
Uses
N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:
- In the iridium catalyzed allylic arylation.
- To prepare a copper complex (Cu2X2L3), which is used to detect the transmetalation intermediates in asymmetric addition reactions using ZnEt2.
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][Supplier
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Tianjin Derchemist Science & Technology Co., Ltd.
- Tel
- 22-58627059 13920586291
- zdcomcon@126.com
Shanghai Incat Chemtech Co.,Ltd.
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- 021-57603038 13601791340
- 307593986@qq.com
Bide Pharmatech Ltd.
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- 400-1647117 15221909166
- product02@bidepharm.com
Sigma-Aldrich
- Tel
- 021-61415566 800-8193336
- orderCN@merckgroup.com