(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Basic information
- Product Name:
- (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
- Synonyms:
-
- (S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS(1-PHENYLETHYL)AMINE
- (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1S)-1-PHENYLETHYL]AMINE
- (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
- S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,min.95%
- 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
- 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine
- (S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE
- CAS:
- 380230-02-4
- MF:
- C36H30NO2P
- MW:
- 539.6
- Product Categories:
-
- Chiral Phosphine
- CPN
- Mol File:
- 380230-02-4.mol
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(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Chemical Properties
- Melting point:
- 88-89 °C
- alpha
- +13.1° (c 1.01, CHCl3)
- Boiling point:
- 710.7±63.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- pka
- -0.57±0.20(Predicted)
- color
- off-white
- Sensitive
- moisture sensitive
- InChIKey
- LKZPDRCMCSBQFN-UIOOFZCWSA-N
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Safety Information
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
MSDS
- Language:English Provider:SigmaAldrich
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(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Usage And Synthesis
Reaction
- A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
- Iridium-catalyzed regioselective and enantioselective allylation of enamines.
- Iridium-catalyzed asymmetric allylation of KSAc.
Uses
The product may be used as a ligand in:
- Iridium-catalyzed allylic etherification of acyclic, achiral allylic carbonates with potassium silanolates to form chiral allylic alcohols.
- Palladium-catalyzed asymmetric allylic cyclisation of N-tosyl and N-benzyl carbonates to form the corresponding pyrrolidine and piperidine derivatives, respectively.
- Intramolecular iridium-catalyzed allylic cyclizationof (E)-allylic methyl carbonates to form 2,5-trans/cis pyrrolidine derivatives.
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)Supplier
LaaJoo Gold
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- 021-60702684 18516024827
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J & K SCIENTIFIC LTD.
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- 010-82848833 400-666-7788
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Energy Chemical
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- 021-021-58432009 400-005-6266
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China DongFan Chemical Co.,LTD
- Tel
- 86-0571-85151182
Nanjin Cynthia chemicals Technology Co.,Ltd
- Tel
- 0550-5618439 15951861180
- cynthiachem@163.com
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(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)(380230-02-4)Related Product Information
- (+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
- (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
- (R)-MONOPHOS
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
- N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
- (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)