(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Basic information
- Product Name:
- (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
- Synonyms:
-
- (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE
- (S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)METHYLAMINE
- (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
- 3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%
- (S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a
- (S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCL&
- 3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,99%
- 3,4-a′]dinaphthalen-4-yl)MethylaMine
- CAS:
- 490023-37-5
- MF:
- C28H22NO2P
- MW:
- 435.45
- Product Categories:
-
- Chiral Phosphine
- CPN
- Mol File:
- 490023-37-5.mol
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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Chemical Properties
- Melting point:
- 155-159 °C
- alpha
- +356° (c 0.32, CHCl3)
- Boiling point:
- 635.4±48.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- pka
- 0.08±0.20(Predicted)
- color
- white
- Sensitive
- moisture sensitive
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Safety Information
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
MSDS
- Language:English Provider:SigmaAldrich
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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) Usage And Synthesis
Reaction
- The ligand has been used in Ir-catalyzed asymmetric hydrogenation of substituted benzophenone N-H imines.
- The ligand has been used in the rhodium-catalyzed enantioselective hydrogenation of (E)-N-acylated dehydro-β-aminoacid esters.
Uses
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)Supplier
J & K SCIENTIFIC LTD.
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- 010-82848833 400-666-7788
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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- 021-61259108 18621169109
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Energy Chemical
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- 021-021-58432009 400-005-6266
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Shanghai Incat Chemtech Co.,Ltd.
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- 021-57603038 13601791340
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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)(490023-37-5)Related Product Information
- Benzophenone
- (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
- (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
- (R)-MONOPHOS
- (+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
- (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)