2,2-Di(tert-butylperoxy)butane Chemical Properties

Melting point:

≥80 °C (SADT)

Boiling point:

296.66°C (rough estimate)

Density 

0.88 g/mL at 25 °C

vapor pressure 

50Pa at 25℃

refractive index 

n20/D 1.445

Flash point:

118 °F

storage temp. 

Refrigerator (+4°C) + Flammables area

form 

Solution

color 

Clear

Water Solubility 

immiscible

Stability:

Unstable. Solid material may explode if heated, struck or mixed with other chemicals. Do not grind! Incompatible with acids, bases, strong oxidizing agents, powdered metals, strong reducing agents.

LogP

5.4 at 30℃

NIST Chemistry Reference

2,2-Bis(tert-butylperoxy) butane(2167-23-9)

EPA Substance Registry System

Peroxide, 1,1'-(1-methylpropylidene)bis[2-(1,1-dimethylethyl) (2167-23-9)

Safety Information

Hazard Codes 

O,Xi

Risk Statements 

8-41-7-36/38-10-37/38-65

Safety Statements 

16-17-26-36/37/39-3/7-14A-14-45

RIDADR 

UN 3103 5.2

WGK Germany 

2

HazardClass 

5.2

PackingGroup 

II

HS Code 

29096000

MSDS

• Language:English Provider:Trigonox D
• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich

2,2-Di(tert-butylperoxy)butane Usage And Synthesis

Chemical Properties

(usually handled as a solution in mineral oil)

Reactivity Profile

Peroxides, such as 2,2-Di(tert-butylperoxy)butane, are good oxidizing agents. Organic compounds can ignite on contact with concentrated peroxides. Strongly reduced material such as sulfides, nitrides, and hydrides may react explosively with peroxides. There are few chemical classes that do not at least produce heat when mixed with peroxides. Many produce explosions or generate gases (toxic and nontoxic). Generally, dilute solutions of peroxides (<70%) are safe, but the presence of a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium) as an impurity may even then cause rapid decomposition, a buildup of heat, and even an explosion. Solutions of peroxides often become explosive when evaporated to dryness or near-dryness. Danger of explosion when dry. May explode from heat, shock, friction or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.). May be ignited by heat, sparks or flames.

Flammability and Explosibility

Not classified

2,2-Di(tert-butylperoxy)butane(2167-23-9)Related Product Information

• 2-Bromo-2-methylpropane
• Dibutyl phthalate
• BUTYL OLEATE
• 2-Chloro-2-methylpropane
• Cyhalofop-butyl
• Butyl acetate
• Diethylene glycol monobutyl ether
• Bis(tributyltin) oxide
• tert-Butanol
• Tetrabutylammonium hydroxide
• Buprofezin
• tert-Butyl hydroperoxide
• Di-tert-butyl peroxide
• Dibutyltin oxide
• 1 1-BIS(TERT-AMYLPEROXY)CYCLOHEXANE
• 2,2-DI(4,4-DI(TERT-BUTYLPEROXY)CYCLOHEXYL)PROPANE, 20 WT% SOLUTION IN ETHYLBENZENE
• Butyl 4,4-bis(tert-butyldioxy)valerate
• 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane