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5-AMINO-1-NAPHTHOL-3-SULFONIC ACID

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5-AMINO-1-NAPHTHOL-3-SULFONIC ACID Basic information

Product Name:
5-AMINO-1-NAPHTHOL-3-SULFONIC ACID
Synonyms:
  • M ACID
  • 1-AMINO-5-NAPHTHOL-7-SULFONIC ACID
  • 5-AMINO-1-NAPHTHOL-3-SULFONIC ACID
  • 8-AMINO-4-HYDROXY-2-NAPHTHALENESULFONIC ACID
  • 8-amino-4-hydroxynaphthalene-2-sulphonic acid
  • 8-amino-4-hydroxynaphthalene-2-sulfonic acid
  • 8-azanyl-4-hydroxy-naphthalene-2-sulfonic acid
  • 8-Amino-4-hydroxy-2-naphthalenesulfonic Acid M Acid
CAS:
489-78-1
MF:
C10H9NO4S
MW:
239.25
EINECS:
207-700-7
Product Categories:
  • Intermediates of Dyes and Pigments
Mol File:
489-78-1.mol
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5-AMINO-1-NAPHTHOL-3-SULFONIC ACID Chemical Properties

Density 
1.627±0.06 g/cm3(Predicted)
pka
-0.35±0.40(Predicted)
form 
powder to crystal
color 
White to Amber to Dark purple
CAS DataBase Reference
489-78-1(CAS DataBase Reference)
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
HS Code 
2930909899
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5-AMINO-1-NAPHTHOL-3-SULFONIC ACID Usage And Synthesis

Chemical Properties

1-Amino-5-hydroxynaphthalene-7-sulfonic acid [489-78-1].  (8-amino-4-hydroxynaphthalene-2-sulfonic acid), M acid, C10H9NO4S, Mr 239.2, and its sodium salt are sparingly soluble in water. Coupling with diazo compounds takes place under acidic and alkaline conditions, but a bisazo derivative cannot be obtained. Reaction with bisulfite gives 4,8-dihydroxynaphthalene-2-sulfonic acid.

Production Methods

1-Aminonaphthalene-5,7-disulfonic acid is heated with concentrated sodium hydroxide for 16 h at 172 – 176℃. After the reaction mixture is quenched, acidified, and purged of sulfur dioxide, the product is isolated in 80 % yield.

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