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Manganic acetylacetonate

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Manganic acetylacetonate Basic information

Product Name:
Manganic acetylacetonate
Synonyms:
  • MANGANESE(III) 2,4-PENTANEDIONATE
  • MANGANESE(III) ACETYLACETONATE
  • MANGANIC ACETYLACETONATE
  • ACETYLACETONE, MANGANESE(III)DERIVATIVE
  • ACETYLACETONE MANGANESE(III) SALT
  • 2,4-PENTANEDIONE, MANGANESE(III) DERIVATIVE
  • TRIS(2,4-PENTANEDIONATO)MANGANESE(3)
  • TRIS(2,4-PENTANEDIONATO)MANGANESE(III)
CAS:
14284-89-0
MF:
C15H21MnO6
MW:
352.26
EINECS:
238-188-3
Product Categories:
  • metal beta-diketonate complexes
  • Classes of Metal Compounds
  • Mn (Manganese) Compounds
  • Transition Metal Compounds
Mol File:
14284-89-0.mol
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Manganic acetylacetonate Chemical Properties

Melting point:
159-161 °C (dec.)(lit.)
storage temp. 
Store at room temperature
solubility 
Soluble in benzene, ethyl acetate
form 
Crystalline Powder
color 
Black
Sensitive 
Hygroscopic
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Exposure limits
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
Stability:
hygroscopic
NIST Chemistry Reference
Manganic acetylacetonate(14284-89-0)
EPA Substance Registry System
Manganese, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14284-89-0)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
22-36/37/38-20/21/22
Safety Statements 
36/37/39-26
WGK Germany 
3
TSCA 
Yes
HS Code 
29141900

MSDS

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Manganic acetylacetonate Usage And Synthesis

Chemical Properties

black crystalline powder

Uses

It is mainly used as a solvent in paint and a precursor to vitamin E.

General Description

Manganese(III) Acetylacetonate is a one-electron oxidant used to oxidize phenols, β-dicarbonyl compounds, and thiols to the corresponding radical.

reaction suitability

core: manganese
reagent type: catalyst

Solubility in organics

Manganic acetylacetonate is slightly soluble in water; soluble in acetone, benzene, chloroform, ether, ethanol, ethyl acetate.

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