Cupric acetylacetonate Chemical Properties

Melting point:

284-288 °C (dec.) (lit.)

Boiling point:

160 °C (9.7513 mmHg)

Density 

0.721 g/cm3

bulk density

200-400kg/m3

vapor pressure 

0.13 hPa (163 °C)

Flash point:

160°C/10mm

storage temp. 

Store below +30°C.

solubility 

0.2g/l

form 

Crystalline Powder

Specific Gravity

1.594

color 

Blue to blue-grayish

Water Solubility 

0.2 g/L (20 ºC)

Hydrolytic Sensitivity

4: no reaction with water under neutral conditions

Sublimation 

160 ºC

BRN 

4157957

Exposure limits

ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3

Stability:

Stable. Incompatible with strong oxidizing agents.

NIST Chemistry Reference

Copper, bis(2,4-pentanedionato-o,o')-(13395-16-9)

EPA Substance Registry System

Copper, bis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-4-1)- (13395-16-9)

Safety Information

Hazard Codes 

Xi,Xn

Risk Statements 

36/37/38-20/21/22

Safety Statements 

26-36-36/37/39

WGK Germany 

3

RTECS 

GL6520000

TSCA 

Yes

HS Code 

29420000

Hazardous Substances Data

13395-16-9(Hazardous Substances Data)

Toxicity

LD50 ipr-mus: 19 mg/kg CHTHBK 16,371,71

MSDS

• Language:English Provider:Cupric acetylacetonate
• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

Cupric acetylacetonate Usage And Synthesis

Chemical Properties

crystalline solid

Uses

Copper(II) acetylacetonate catalyzes coupling and carbene transfer reactions. Metal acetylacetonates are used as catalysts for polymerization of olefins and transesterification. They are used as PVC stabilizer. They are used as curing agents for epoxy resins, acrylic adhesives and silicone rubbers. They are used as solvents, lubricant additives, paint drier, and pesticides. They are used in glass coatings.

Definition

Crystalline powder, slightly soluble in water and alcohol, soluble in chloroform, mp >230C. Resistant to hydrolysis. A chelating nonionizing compound.

reaction suitability

core: copper
reagent type: catalyst

Safety Profile

Poison by intravenous andintraperitoneal routes. When heated to decomposition it emits acrid smoke andfumes of Cu.

Cupric acetylacetonate(13395-16-9)Related Product Information

• ZIRCONIUM(IV) ACETYLACETONATE
• Acetylacetone
• Platinum bis(acetylacetonate)
• Cobaltic acetylacetonate
• Aluminum acetylacetonate
• Copper
• Ethyl 2,4-dioxovalerate
• Cupric oxide
• Vanadyl acetylacetonate
• VANADIUM(III) ACETYLACETONATE
• Bis(acetylacetonato)cobalt
• Ferric acetylacetonate
• Copper oxychloride
• Calcium acetylacetonate
• Ferrous acetylacetonate
• Acetylacetonatobis(ethylene)rhodium(I)
• Zinc(II) acetylacetonate
• Titanium(IV)oxide acetylacetonate