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Cupric acetylacetonate

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Cupric acetylacetonate Basic information

Product Name:
Cupric acetylacetonate
Synonyms:
  • COPPERACETONYLACETONATE
  • COPPER ACETYLACETONATE
  • COPPER(+2)ACETYLACETONATE
  • COPPER(II) ACETYLACETONATE
  • COPPER(II) 2,4-PENTANEDIONATE
  • CUPRIC(II) ACETYLACETONATE
  • CUPRIC AA
  • CUPRIC ACETYLACETONATE
CAS:
13395-16-9
MF:
C10H14CuO4
MW:
261.76
EINECS:
236-477-9
Product Categories:
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Cu (Copper) Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Synthetic Organic Chemistry
  • Pharmaceutical Intermediates
  • Organometallics
  • Transition Metal Compounds
  • metal beta-diketonate complexes
  • proteins
Mol File:
13395-16-9.mol
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Cupric acetylacetonate Chemical Properties

Melting point:
284-288 °C (dec.) (lit.)
Boiling point:
160 °C (9.7513 mmHg)
Density 
0.721 g/cm3
vapor pressure 
0.13 hPa (163 °C)
Flash point:
160°C/10mm
storage temp. 
Store below +30°C.
solubility 
0.2g/l
form 
Crystalline Powder
Specific Gravity
1.594
color 
Blue to blue-grayish
Water Solubility 
0.2 g/L (20 ºC)
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Sublimation 
160 ºC
BRN 
4157957
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
Stability:
Stable. Incompatible with strong oxidizing agents.
NIST Chemistry Reference
Copper, bis(2,4-pentanedionato-o,o')-(13395-16-9)
EPA Substance Registry System
Copper, bis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-4-1)- (13395-16-9)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-36-36/37/39
WGK Germany 
3
RTECS 
GL6520000
TSCA 
Yes
HS Code 
29420000
Hazardous Substances Data
13395-16-9(Hazardous Substances Data)
Toxicity
LD50 ipr-mus: 19 mg/kg CHTHBK 16,371,71

MSDS

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Cupric acetylacetonate Usage And Synthesis

Chemical Properties

crystalline solid

Uses

Copper(II) acetylacetonate catalyzes coupling and carbene transfer reactions. Metal acetylacetonates are used as catalysts for polymerization of olefins and transesterification. They are used as PVC stabilizer. They are used as curing agents for epoxy resins, acrylic adhesives and silicone rubbers. They are used as solvents, lubricant additives, paint drier, and pesticides. They are used in glass coatings.

Definition

Crystalline powder, slightly soluble in water and alcohol, soluble in chloroform, mp >230C. Resistant to hydrolysis. A chelating nonionizing compound.

Safety Profile

Poison by intravenous andintraperitoneal routes. When heated to decomposition it emits acrid smoke andfumes of Cu.

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