ChemicalBook > Product Catalog > Organic Chemistry > Amides > Acyclic polyamines and their derivatives > DIMETHYLSILYLDIETHYLAMINE
DIMETHYLSILYLDIETHYLAMINE
DIMETHYLSILYLDIETHYLAMINE Basic information
- Product Name:
- DIMETHYLSILYLDIETHYLAMINE
- Synonyms:
-
- N,N-DIETHYL-1,1-DIMETHYLSILYLAMINE
- DIETHYLAMINODIMETHYLSILANE
- DIMETHYLSILYLDIETHYLAMINE
- Silanamine,N,N-diethyl-1,1-dimethyl-
- n,n-diethyl-1,1-dimethyl-silanamin
- N,N-Diethyldimethylsilanamine
- N,N-diethyl-1,1-dimethyl-Silanamine
- N-dimethylsilyl-N-ethylethanamine
- CAS:
- 13686-66-3
- MF:
- C6H17NSi
- MW:
- 131.29
- EINECS:
- 237-202-5
- Product Categories:
-
- Chemical Synthesis
- Organometallic Reagents
- Organometallic Reagents
- Organosilicon
- Others
- Mol File:
- 13686-66-3.mol
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DIMETHYLSILYLDIETHYLAMINE Chemical Properties
- Boiling point:
- 109 °C
- Density
- 0.8
- refractive index
- 1.4080
- Flash point:
- <-5°C
- solubility
- sol common aprotic organic solvents.
- pka
- 9.05±0.70(Predicted)
- Specific Gravity
- 0.8
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- Sensitive
- Moisture Sensitive
- BRN
- 741862
- EPA Substance Registry System
- Silanamine, N,N-diethyl-1,1-dimethyl- (13686-66-3)
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Safety Information
- Hazard Codes
- F,Xi
- Risk Statements
- 11-36/37/38
- Safety Statements
- 16-23-26-36
- RIDADR
- 1993
- WGK Germany
- 3
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- II
MSDS
- Language:English Provider:ALFA
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DIMETHYLSILYLDIETHYLAMINE Usage And Synthesis
Physical properties
bp 112°C/760 mmHg; n20 D 1.4087; d20 4 0.7505 g cm?3.
Uses
N,N-Diethylaminodimethylsilane is a
useful reagent for the conversion of hydroxy groups of allyl
or homoallyl alcohols into hydrodimethylsilyl ethers for use in
intramolecular hydrosilation reactions. In some cases, N,N-diethylaminodimethylsilane
gives superior results compared to the
more commonly employed 1,1,3,3-tetramethyldisilazane (eq 1).
Preparation
by treatment of commercially available chlorodimethylsilane (ClMe2SiH) and diethylamine in the presence of triethylamine in ether, followed by filtration and distillation.
DIMETHYLSILYLDIETHYLAMINESupplier
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
- market03@meryer.com
Alfa Aesar
- Tel
- 400-6106006
- saleschina@alfa-asia.com
BeiJing Hwrk Chemicals Limted
- Tel
- 0757-86329057 18934348241
- sales4.gd@hwrkchemical.com
Shanghai Hanhong Scientific Co.,Ltd.
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
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DIMETHYLSILYLDIETHYLAMINE(13686-66-3)Related Product Information
- DIMETHYLSILYLDIETHYLAMINE
- 1-TRIMETHYLSILYL-2-PYRROLIDINONE
- 1-(TRIMETHYLSILYL)PYRROLIDINE
- N,N-Diethyl-1,1,1-trimethylsilylamine
- BIS(DIETHYLAMINO)DIMETHYLSILANE
- 4-(Trimethylsilyl)morpholine
- N-PiperidinoTrimethylsilane
- Diethoxymethylsilane
- N-(TERT-BUTYLDIMETHYLSILYL)PHTHALIMIDE
- (4R)-N-(TERT-BUTYLDIMETHYLSILYL)AZETIDIN-2-ONE-4-CARBOXYLIC ACID
- ALLYL(DIISOPROPYLAMINO)DIMETHYLSILANE
- PENTAFLUOROPHENYLDIMETHYLSILYLDIETHYLAMINE
- (4S)-N-(TERT-BUTYLDIMETHYLSILYL)AZETIDIN-2-ONE-4-CARBOXYLIC ACID
- BIS-N,N'-(TRIMETHYLSILYL)PIPERAZINE
- (DIISOPROPYLAMINO)TRIMETHYLSILANE
- 1-CYANOETHYL(DIETHYLAMINO)DIMETHYLSILANE
- N-TRIMETHYLSILYLPHTHALIMIDE
- CHLORO(DIISOPROPYLAMINO)DIMETHYLSILANE, 97