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Diethoxymethylsilane

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Diethoxymethylsilane Basic information

Product Name:
Diethoxymethylsilane
Synonyms:
  • DEMS
  • Methyldiethoxysilane (PURITY??)
  • diethoxymethyl-silan
  • Silane, diethoxymethyl-
  • Diethoxymethylsilane [Hydrosilylating Reagent]
  • Diethoxymethylsilane. Methylhydrogendiethoxysilane.
  • Methyldiethoxysilane,97%
  • Methyldiethoxysilane >=96%
CAS:
2031-62-1
MF:
C5H14O2Si
MW:
134.25
EINECS:
217-982-3
Product Categories:
  • Alkoxy Silanes
  • Hydrogensilanes Hydrogensiloxanes
  • Reduction
  • Si (Classes of Silicon Compounds)
  • Si-H Compounds
  • Reducing Agents
  • Dialkoxysilanes
  • Silicon Compounds (for Synthesis)
  • Si-O Compounds
  • Synthetic Organic Chemistry
Mol File:
2031-62-1.mol
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Diethoxymethylsilane Chemical Properties

Melting point:
98 °C
Boiling point:
94-95 °C (lit.)
Density 
0.838 g/mL at 20 °C (lit.)
vapor pressure 
0.053-7910Pa at 25℃
refractive index 
1.3760
Flash point:
10°C
storage temp. 
Flammables area
form 
clear liquid
color 
Colorless to Almost colorless
Specific Gravity
0.829
Water Solubility 
Miscible with water, 1,4-dioxane, tetrahydrofuran, acetonitrile, dichloromethane, chloroform, dimethyl sulfoxide, hexamethylphosphoric triamide and toluene. Insoluble in diethyl ether and hexane.
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
BRN 
1733975
LogP
-2.4-1.7 at 20℃
CAS DataBase Reference
2031-62-1(CAS DataBase Reference)
NIST Chemistry Reference
Methyldiethoxysilane(2031-62-1)
EPA Substance Registry System
Silane, diethoxymethyl- (2031-62-1)
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Safety Information

Hazard Codes 
F,Xi
Risk Statements 
11-36/37/38
Safety Statements 
16-26-36
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29319090

MSDS

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Diethoxymethylsilane Usage And Synthesis

Chemical Properties

Colorless clear liquid

Uses

Diethoxymethylsilane is used in the preparation of N,N'-methylsilanediyl-bis-phthalimide by reacting with phthalimide. It is used as a reagent in the selective reduction of carbonyl compounds, hydorosilylation of alkenes, tandem reductive aldol reaction and rhodium-catalyszed silylcarbocyclization.

Flammability and Explosibility

Flammable

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