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4,4'-DIAMINO-3,3'-DIMETHYLDIPHENYLMETHANE

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4,4'-DIAMINO-3,3'-DIMETHYLDIPHENYLMETHANE Basic information

Product Name:
4,4'-DIAMINO-3,3'-DIMETHYLDIPHENYLMETHANE
Synonyms:
  • 4-[(4-aminophenyl)methyl]-2-methylaniline
  • 4,4’-methylenebis(2-methyl-anilin
  • 4,4’-methylenebis(2-methyl-benzenamin
  • 4,4’-methylenebis(2-methylbenzenamine)
  • 4,4’-methylenebis[2-methyl-benzenamin
  • 4,4’-methylenedi-o-toluidin
  • bis(4-amino-3-methylphenyl)-methan
  • bis(4-amino-3-methylphenyl)methane
CAS:
838-88-0
MF:
C15H18N2
MW:
226.32
EINECS:
212-658-8
Product Categories:
  • Diphenylmethanes (for High-Performance Polymer Research)
  • Functional Materials
  • Industrial/Fine Chemicals
  • Reagent for High-Performance Polymer Research
Mol File:
838-88-0.mol
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4,4'-DIAMINO-3,3'-DIMETHYLDIPHENYLMETHANE Chemical Properties

Melting point:
155-157 °C
Boiling point:
357.94°C (rough estimate)
Density 
0.9543 (rough estimate)
vapor pressure 
1.8hPa at 205.5℃
refractive index 
1.5000 (estimate)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
Water Solubility 
Insoluble in water
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
5.18±0.25(Predicted)
color 
White to Light yellow to Light orange
BRN 
398069
InChIKey
WECDUOXQLAIPQW-UHFFFAOYSA-N
CAS DataBase Reference
838-88-0(CAS DataBase Reference)
IARC
2B (Vol. 4, Sup 7) 1987
EPA Substance Registry System
4,4'-Methylenebis(2-methylaniline) (838-88-0)
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Safety Information

Hazard Codes 
T,N
Risk Statements 
45-22-43-50/53
Safety Statements 
53-45-60-61
RIDADR 
UN 3077 9/PG 3
WGK Germany 
3
RTECS 
BY5300000
10-23
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29215900

MSDS

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4,4'-DIAMINO-3,3'-DIMETHYLDIPHENYLMETHANE Usage And Synthesis

Chemical Properties

White powder. Soluble in ethanol and hot water.

Uses

4,4′-Methylene-bis(2-methylaniline) has been used as a reference standard for the determination of 4,4′-methylene-bis(2-methylaniline) in plastic multilayer food packaging materials by liquid chromatography (LC)-Orbitrap-full scan-high resolution mass spectrometry (HRMS).
It may be used as a reference standard for the analysis of 4,4′-methylene-bis(2-methylaniline) in dyes, cosmetics, finger paints and inks for pens and tattoos by LC-MS.

Uses

4,4'-Diamino-3,3'-dimethyldiphenylmethane can be used for preparation polyimide and epoxy resin material.

Definition

ChEBI: 4,4'-Methylene bis(2-methylaniline) is a diarylmethane.

General Description

4,4′-Methylene-bis(2-methylaniline) belongs to the primary aromatic amines (PAAs) family of compounds which are toxic in nature and are probable human carcinogens.

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by ingestion. An eye irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.

4,4'-DIAMINO-3,3'-DIMETHYLDIPHENYLMETHANESupplier

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