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p-Nitrobenzamide

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p-Nitrobenzamide Basic information

Product Name:
p-Nitrobenzamide
Synonyms:
  • p-nitro-benzamid
  • P-NITROBENZAMIDE
  • TIMTEC-BB SBB008201
  • 4-Nitrobenzamide p-Nitrobenzamide
  • 4-Nitrobenzamide>99.0%
  • 4-NITROBENZAMIDE
  • 4-Nitrobenzamide, 98+%
  • 4-Carbamoylnitrobenzene
CAS:
619-80-7
MF:
C7H6N2O3
MW:
166.13
EINECS:
210-613-7
Product Categories:
  • Pharmaceutical Intermediates
  • Amides
  • Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
  • Carbonyl Compounds
  • Organic Building Blocks
Mol File:
619-80-7.mol
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p-Nitrobenzamide Chemical Properties

Melting point:
199-201 °C(lit.)
Boiling point:
294.32°C (rough estimate)
Density 
1.4334 (rough estimate)
refractive index 
1.5880 (estimate)
pka
15.02±0.50(Predicted)
form 
powder to crystal
color 
White to Orange to Green
Water Solubility 
<0.01 g/100 mL at 18 ºC
BRN 
639263
Stability:
Stable. Incompatible with strong oxidizing agents, strong bases.
CAS DataBase Reference
619-80-7(CAS DataBase Reference)
NIST Chemistry Reference
Benzamide, 4-nitro-(619-80-7)
EPA Substance Registry System
p-Nitrobenzamide (619-80-7)
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Safety Information

Hazard Codes 
T,Xn
Risk Statements 
23/24/25-22-20/21/22
Safety Statements 
27-28-36/37/39-45-36
WGK Germany 
3
RTECS 
CV5601000
TSCA 
Yes
HS Code 
29242990

MSDS

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p-Nitrobenzamide Usage And Synthesis

Chemical Properties

white powder

Uses

4-Nitrobenzamide was used in the preparation of 4-nitrobenziminosulfurane.

Synthesis Reference(s)

Tetrahedron Letters, 36, p. 3469, 1995 DOI: 10.1016/0040-4039(95)00528-K

General Description

White powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

A nitrated amide. Organic amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).

Fire Hazard

Flash point data for p-Nitrobenzamide are not available, however, p-Nitrobenzamide is probably combustible.

p-NitrobenzamideSupplier

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