p-Nitrobenzamide Chemical Properties

Melting point:

199-201 °C(lit.)

Boiling point:

294.32°C (rough estimate)

Density 

1.4334 (rough estimate)

refractive index 

1.5880 (estimate)

pka

15.02±0.50(Predicted)

form 

powder to crystal

color 

White to Orange to Green

Water Solubility 

<0.01 g/100 mL at 18 ºC

BRN 

639263

Stability:

Stable. Incompatible with strong oxidizing agents, strong bases.

CAS DataBase Reference

619-80-7(CAS DataBase Reference)

NIST Chemistry Reference

Benzamide, 4-nitro-(619-80-7)

EPA Substance Registry System

p-Nitrobenzamide (619-80-7)

Safety Information

Hazard Codes 

T,Xn

Risk Statements 

23/24/25-22-20/21/22

Safety Statements 

27-28-36/37/39-45-36

WGK Germany 

3

RTECS 

CV5601000

TSCA 

Yes

HS Code 

29242990

MSDS

• Language:English Provider:4-Nitrobenzamide
• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

p-Nitrobenzamide Usage And Synthesis

Chemical Properties

white powder

Uses

4-Nitrobenzamide was used in the preparation of 4-nitrobenziminosulfurane.

Synthesis Reference(s)

Tetrahedron Letters, 36, p. 3469, 1995 DOI: 10.1016/0040-4039(95)00528-K

General Description

White powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

A nitrated amide. Organic amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).

Fire Hazard

Flash point data for p-Nitrobenzamide are not available, however, p-Nitrobenzamide is probably combustible.

p-Nitrobenzamide(619-80-7)Related Product Information

• Benzamide
• 4-Nitrobenzonitrile
• p-Aminobenzamide
• 4-Nitrobenzoic acid
• Chlorantraniliprole
• 4-Nitrobenzoyl chloride
• p-Nitrobenzamide
• 4-Nitroanisole
• N-(4-Nitrobenzoyl)-beta-alanine
• 4-NITROBENZHYDRAZIDE
• 2-CHLORO-4-NITROBENZAMIDE
• P-NITROBENZOYL-L-GLUTAMIC ACID
• 4-Nitrophthalhydrazide
• 4-Nitrophthalimide
• 3-METHYL-4-NITROBENZAMIDE
• 4-NITROHIPPURIC ACID
• N-cyclohexyl 3-borono-5-nitrobenzamide
• N-benzyl 3-borono-5-nitrobenzamide