Iodomethyl pivalate Chemical Properties

Melting point:

33-35 °C(lit.)

Boiling point:

211.5 °C(lit.)

Density 

1.614±0.06 g/cm3(Predicted)

refractive index 

1.4830 to 1.4870

Flash point:

194 °F

storage temp. 

Refrigerator, under inert atmosphere

solubility 

Chloroform (Slightly), Methanol (Slightly)

form 

Oil

color 

Yellow

Sensitive 

Light, Air and Heat Sensitive

InChI

InChI=1S/C6H11IO2/c1-6(2,3)5(8)9-4-7/h4H2,1-3H3

InChIKey

PELJISAVHGXLAL-UHFFFAOYSA-N

SMILES

C(OCI)(=O)C(C)(C)C

CAS DataBase Reference

53064-79-2(CAS DataBase Reference)

Safety Information

RIDADR 

UN 3265 8/PG III

WGK Germany 

3

HS Code 

2915.90.5050

HazardClass 

8

PackingGroup 

III

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

Iodomethyl pivalate Usage And Synthesis

Chemical Properties

Pale Yellow Liquid

Uses

Iodomethyl pivalate can be used as reagent used for the addition of pivaloyl group.

Synthesis Reference(s)

The Journal of Organic Chemistry, 48, p. 5280, 1983 DOI: 10.1021/jo00174a024

Synthesis

Iodomethyl pivalate is synthesised using chloromethyl pivalate as a raw material by chemical reaction. The specific synthesis steps are as follows:
Three bottles were added 10.0 g of chloromethyl pivalate, Ethyl acetate 30 mL, 11.6 g of sodium iodide and 3.6 g of calcium chloride, After heating to 78 ° C for 6 h, Cooling to 0 ,Then washed with 5% sodium thiosulfate to colorless, Dried over anhydrous magnesium sulfate, Concentrated under reduced pressure. 16 g of a yellow liquid. Iodomethyl pivalate was obtained. The reaction molar yield was 94% and GC: 98%.

Iodomethyl pivalate(53064-79-2)Related Product Information

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