2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Chemical Properties

Boiling point:

70 °C/2 mmHg (lit.)

Density 

1.229 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.456(lit.)

Flash point:

205 °F

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

form 

clear liquid

color 

Colorless to Light yellow

Specific Gravity

1.229

Hydrolytic Sensitivity

7: reacts slowly with moisture/water

InChIKey

XBHPFCIWRHJDCP-UHFFFAOYSA-N

Safety Information

Hazard Codes 

C

Risk Statements 

34

Safety Statements 

26-27-36/37/39-45

RIDADR 

UN 3265 8/PG 2

WGK Germany 

3

HazardClass 

8

PackingGroup 

Ⅱ

HS Code 

29319090

MSDS

• Language:English Provider:SigmaAldrich

2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Usage And Synthesis

Physical properties

bp 70 °C/2 mmHg; d 1.229 g mL?1

Uses

2-(Trimethylsilyl)phenyl trifluoromethanesulfonate may be used to generate benzyne under mild conditions of simple fluoride treatment at room temperature.

Uses

2-(Trimethylsilyl)phenyl Triflate is a useful reagent applied in reactions of Polycyclic Arenes, Heteroatom Arylation,Heteroarenes and Benzannulated Heterocycles, Carbon Arylations, etc.

General Description

2-(Trimethylsilyl)phenyl trifluoromethanesulfonate is an important ortho-benzyne precursor in aryne chemistry.

2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE(88284-48-4)Related Product Information

• Phenyl trifluoromethanesulfonate
• Trifluoromethane
• 4-METHOXY-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,4-METHOXY-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,95.0+%(GC)
• 3-METHOXY-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,95.0+%(GC),3-Methoxy-2-(trimethylsilyl)phenyl Trifluoromethanesulfonate
• 1-(TRIMETHYLSILYL)-2-NAPHTHYL TRIFLATE
• 4-METHYL-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,4-METHYL-2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,98.0+%(GC)
• 2-METHYL-6-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE,96.0+%(GC),2-METHYL-6-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
• 1,3,5-TRIS[4-(TRIFLUOROMETHANESULFONYLOXY)-3-(TRIMETHYLSILYL)PHENYL]BENZENE
• 2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
• 3-(TRIMETHYLSILYL)-2-NAPHTHYL TRIFLUOROMETHANESULFONATE
• 3,3''-BIS-(TRIMETHYLSILYL)BIPHENYL-4,4''-DIYL BIS(TRIFLUOROMETHANESULFONATE)