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Dichloro(1,5-cyclooctadiene)palladium(II)

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Dichloro(1,5-cyclooctadiene)palladium(II) Basic information

Product Name:
Dichloro(1,5-cyclooctadiene)palladium(II)
Synonyms:
  • dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]-palladiu
  • (1,5-CYCLOOCTADIENE)PALLADIUM(II)CHLORIDE
  • 1,5-CYCLOOCTADIENEPALLADIUM(II) DICHLORIDE
  • DICHLORO(CYCLOOCTA-1,5-DIENE)PALLADATE (II)
  • DICHLORO(CYCLOOCTA-1,5-DIENE)PALLADIUM(II)
  • DICHLORO(ETA-CYCLOOCTA-1,5-DIENE)PALLADIUM (II)
  • DICHLORO(1,5-CYCLOOCTYLDIENE)PALLADIUM(II)
  • DICHLORO(1,5-CYCLOOCTADIENE)PALLADIUM(II)
CAS:
12107-56-1
MF:
C8H12Cl2Pd
MW:
285.51
EINECS:
235-161-8
Product Categories:
  • chemical reaction,pharm,electronic,materials
  • organometallic complexes
  • Catalysts for Organic Synthesis
  • Catalysis and Inorganic Chemistry
  • Homogeneous Pd Catalysts
  • Palladium
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Pd (Palladium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Pd
Mol File:
12107-56-1.mol
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Dichloro(1,5-cyclooctadiene)palladium(II) Chemical Properties

Melting point:
210 °C (dec.) (lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble in dichloromethane
form 
crystal
color 
yellow
Water Solubility 
insoluble
Sensitive 
Hygroscopic
InChI
InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
InChIKey
NEKYMUKEOUDFPP-XRGHXPOKSA-L
SMILES
C1CC=CCCC=C1.[Pd](Cl)Cl |c:2,6|
CAS DataBase Reference
12107-56-1(CAS DataBase Reference)
EPA Substance Registry System
Palladium, dichloro[(1,2,5,6-.eta.)-1,5-cyclooctadiene]- (12107-56-1)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
TSCA 
Yes
HS Code 
28439000

MSDS

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Dichloro(1,5-cyclooctadiene)palladium(II) Usage And Synthesis

Chemical Properties

yellow

Uses

Dichloro(1,5-cyclooctadiene)palladium(II) is used as catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes, Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate and methoxycarbonylation of iodobenzene.

Uses

Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation. It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes; the synthesis of benzo[b]thiophenes from thioenols and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.

Dichloro(1,5-cyclooctadiene)palladium(II) Preparation Products And Raw materials

Raw materials

Dichloro(1,5-cyclooctadiene)palladium(II)Supplier

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