Dichloro(1,5-cyclooctadiene)palladium(II)
Dichloro(1,5-cyclooctadiene)palladium(II) Basic information
- Product Name:
- Dichloro(1,5-cyclooctadiene)palladium(II)
- Synonyms:
-
- dichloro[(1,2,5,6-eta)-1,5-cyclooctadiene]-palladiu
- (1,5-CYCLOOCTADIENE)PALLADIUM(II)CHLORIDE
- 1,5-CYCLOOCTADIENEPALLADIUM(II) DICHLORIDE
- DICHLORO(CYCLOOCTA-1,5-DIENE)PALLADATE (II)
- DICHLORO(CYCLOOCTA-1,5-DIENE)PALLADIUM(II)
- DICHLORO(ETA-CYCLOOCTA-1,5-DIENE)PALLADIUM (II)
- DICHLORO(1,5-CYCLOOCTYLDIENE)PALLADIUM(II)
- DICHLORO(1,5-CYCLOOCTADIENE)PALLADIUM(II)
- CAS:
- 12107-56-1
- MF:
- C8H12Cl2Pd
- MW:
- 285.51
- EINECS:
- 235-161-8
- Product Categories:
-
- chemical reaction,pharm,electronic,materials
- organometallic complexes
- Catalysts for Organic Synthesis
- Catalysis and Inorganic Chemistry
- Homogeneous Pd Catalysts
- Palladium
- Classes of Metal Compounds
- Homogeneous Catalysts
- Metal Complexes
- Pd (Palladium) Compounds
- Synthetic Organic Chemistry
- Transition Metal Compounds
- Pd
- Mol File:
- 12107-56-1.mol
Dichloro(1,5-cyclooctadiene)palladium(II) Chemical Properties
- Melting point:
- 210 °C (dec.) (lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Soluble in dichloromethane
- form
- crystal
- color
- yellow
- Water Solubility
- insoluble
- Sensitive
- Hygroscopic
- InChI
- InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
- InChIKey
- NEKYMUKEOUDFPP-XRGHXPOKSA-L
- SMILES
- C1CC=CCCC=C1.[Pd](Cl)Cl |c:2,6|
- CAS DataBase Reference
- 12107-56-1(CAS DataBase Reference)
- EPA Substance Registry System
- Palladium, dichloro[(1,2,5,6-.eta.)-1,5-cyclooctadiene]- (12107-56-1)
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
Dichloro(1,5-cyclooctadiene)palladium(II) Usage And Synthesis
Chemical Properties
yellow
Uses
Dichloro(1,5-cyclooctadiene)palladium(II) is used as catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes, Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate and methoxycarbonylation of iodobenzene.
Uses
Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation. It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes; the synthesis of benzo[b]thiophenes from thioenols and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.
Dichloro(1,5-cyclooctadiene)palladium(II) Preparation Products And Raw materials
Raw materials
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Dichloro(1,5-cyclooctadiene)palladium(II)(12107-56-1)Related Product Information
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