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TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE

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TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE Basic information

Product Name:
TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE
Synonyms:
  • TETRAPHOS-2
  • TETRAPHOS-II
  • TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE
  • (Phosphinetriyl)tris(ethylene)tris(diphenylphosphine)
  • Phosphinetriyltrisethylenetris(diphenylphosphine)
  • Tris[2-(diphenylphosphino)ethyl]phosphine,97%
  • Tris(diphenylphosphinoethyl)phosphine
  • Tris[2-(diphenylphosphino)ethyl]phosphine, 97% 1GR
CAS:
23582-03-8
MF:
C42H42P4
MW:
670.68
EINECS:
245-754-3
Product Categories:
  • Ligand
  • Achiral Phosphine
  • Aryl Phosphine
Mol File:
23582-03-8.mol
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TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE Chemical Properties

Melting point:
134-135 °C(lit.)
Boiling point:
740.1±55.0 °C(Predicted)
form 
Powder
color 
white
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-37/39
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
HS Code 
29310099

MSDS

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TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE Usage And Synthesis

Reaction

  1. Ligand used in the ruthenium-catalyzed hydrogenation of carbon dioxide facilitated by catalytic quantities of bicarbonate.
  2. Ligand used in the selective iron-catalyzed transfer hydrogenation of terminal alkynes.
  3. Ligand used in the selective iron-catalyzed transfer hydrogenation of nitoarenes, without base. 

Chemical Properties

white to light yellow crystal powde

Uses

Ligand used in iron-catalyzed, greener reduction of aldehydes to alcohols under transfer hydrogenation conditions.

Fast and selective iron-catalyzed transfer hydrogenations of aldehydes

General Description

This product has been enhanced for catalytic efficiency.

TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINESupplier

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