ETHYLDIPHENYLPHOSPHINE Chemical Properties

Boiling point:

293 °C(lit.)

Density 

1.048 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.614(lit.)

Flash point:

>230 °F

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

form 

Liquid

color 

Clear colorless

Specific Gravity

1.048

Sensitive 

Air Sensitive

BRN 

744253

InChI

InChI=1S/C14H15P/c1-2-15(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,2H2,1H3

InChIKey

WUOIAOOSKMHJOV-UHFFFAOYSA-N

SMILES

P(CC)(C1=CC=CC=C1)C1=CC=CC=C1

CAS DataBase Reference

607-01-2(CAS DataBase Reference)

EPA Substance Registry System

Phosphine, ethyldiphenyl- (607-01-2)

Safety Information

Hazard Codes 

Xn

Risk Statements 

22-36/37/38

Safety Statements 

26-36

RIDADR 

3278

WGK Germany 

3

RTECS 

SY9242500

F 

10-13-23

HazardClass 

6.1

PackingGroup 

III

HS Code 

29310099

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

ETHYLDIPHENYLPHOSPHINE Usage And Synthesis

Chemical Properties

clear colorless liquid

Uses

Catalyst for:

• Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide
• Regio- and stereoselective hydroalkynylation of methylenecyclopropanes
• Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles
• Dimer to monomer conversion
• Tandem Morita-Baylis-Hillman/Michael addition reactions
• Platinum-catalyzed cyclization
• Regioselective and stereoselective [3+2] cycloaddition
• Platinum-catalyzed intermolecular hydroamination
• Hydroformylation reactions

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

ETHYLDIPHENYLPHOSPHINE(607-01-2)Related Product Information

• ETHYLMALONIC ACID
• Ethanesulfonamide
• 1,2-Bis(diphenylphosphino)ethane
• 1,5-Bis(diphenylphosphino)pentane
• (2-DIMETHYLAMINOETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
• 1,4-Bis(diphenylphosphino)butane
• Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
• Allyltriphenylphosphonium bromide
• BIS(2-DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINE
• (CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE
• TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE
• (+)-DIOP
• (Carbomethoxymethyl)triphenylphosphonium bromide
• 1,3-Bis(diphenylphosphino)propane
• (4-CYANOBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE
• (2S,4S)-4-Diphenylphosphino 2-diphenylphosphinomethyl pyrrolidine
• ETHYLDIPHENYLPHOSPHINE OXIDE
• 2-(Triethoxysilyl)ethyldiphenylphosphine