3-ETHOXY-3-OXOPROPYLZINC BROMIDE Chemical Properties

Density 

0.972 g/mL at 25 °C

Flash point:

1 °F

storage temp. 

2-8°C

Water Solubility 

Reacts with water.

Exposure limits

ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

Safety Information

Hazard Codes 

F,Xi,Xn

Risk Statements 

11-19-36/37-40

Safety Statements 

16-26-29-33-36/37

RIDADR 

UN 3399 4.3/PG 2

WGK Germany 

1

HazardClass 

4.3

PackingGroup 

II

HS Code 

29319090

MSDS

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3-ETHOXY-3-OXOPROPYLZINC BROMIDE Usage And Synthesis

Uses

3-Ethoxy-3-oxopropylzinc bromide is a reagent used to insert ethyl propanoate group to the substrate. It can be used in:

• Synthesis of γ-keto esters from aryl chlorides.
• Synthesis of sulfones from 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO) and alkyl halides.
• Negishi cross-couplings with aryl vinyl phosphates to synthesize 1,1-disubstituted alkenes.

3-ETHOXY-3-OXOPROPYLZINC BROMIDE(193065-68-8)Related Product Information

• 3-FLUOROPHENYLMAGNESIUM BROMIDE
• 2-FLUOROPHENYLZINC IODIDE
• 3-FLUOROPHENYLZINC IODIDE
• 2-ETHYLPHENYLZINC IODIDE
• 4-CHLOROPHENYLZINC IODIDE
• 4-(ETHOXYCARBONYL)PHENYLZINC BROMIDE
• 4-ETHYLPHENYLZINC IODIDE
• 4-N-PENTYLPHENYLZINC IODIDE
• 2-CHLOROPHENYLZINC IODIDE
• 2-METHYLPHENYLZINC IODIDE
• 1-NAPHTHYLZINC IODIDE
• 2-(ETHOXYCARBONYL)PHENYLZINC BROMIDE
• 4-METHYLPHENYLZINC IODIDE
• 6-CHLOROHEXYLZINC BROMIDE
• 3-BROMOPHENYLZINC IODIDE
• 3-ETHOXY-3-OXOPROPYLZINC BROMIDE
• 3-TERT-BUTOXY-3-OXOPROPYLZINC BROMIDE
• N-PROPYLZINC BROMIDE