3-FLUOROPHENYLMAGNESIUM BROMIDE Chemical Properties

Boiling point:

65 °C

Density 

1.024 g/mL at 25 °C

Flash point:

<1 °F

storage temp. 

2-8°C

Water Solubility 

It reacts violently with water.

Sensitive 

Air & Moisture Sensitive

CAS DataBase Reference

17318-03-5

Safety Information

Hazard Codes 

F,C

Risk Statements 

11-14-19-34-22-40-37

Safety Statements 

16-26-33-36/37/39-45-7/8-43

RIDADR 

UN 2924 3/PG 2

WGK Germany 

1

HazardClass 

3

HS Code 

29319090

MSDS

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3-FLUOROPHENYLMAGNESIUM BROMIDE Usage And Synthesis

Chemical Properties

Colorless to yellow to orange to brown liquid

Uses

3-Fluorophenylmagnesium bromide is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Uses

3-Fluorophenylmagnesium bromide is a Grignard reagent that can be used in:

• The preparation of 4-substituted quinazolines by reacting with 2-methylaminobenzonitriles.
• The synthesis of radiolabeled TrkB/C-targeting kinase inhibitor for positron emission tomography (PET) imaging applications.
• Cu-catalyzed carbometalation of substituted cyclopropenes.

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