Basic information Reaction Safety Supplier Related

(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT

Basic information Reaction Safety Supplier Related

(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT Basic information

Product Name:
(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT
Synonyms:
  • (4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT
  • (4R,5R)-(-)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM (IV) DICHLORIDE ACETONITRILE
  • (4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV)dichlorideacetonitrileadduct
  • (4R,5R)-(-)-2,2-DiMethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-diMethanolatotitaniuM(IV) dichloride acetonitrile adduct
  • Dichloro[[(4R,5S)-2,2-dimethyl-1,3-dioxolane-4,5-diyl]bis(di-1-naphthylmethanolato)]titanium
  • [(4R,5R)-5-[hydroxy(dinaphthalen-1-yl)methyl]-2,2-dimethyl-1,3-oxazolidin-4-yl]-dinaphthalen-1-ylmethanol
  • '-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct
  • ane-4,5-dimethanoL
CAS:
197389-47-2
MF:
C49H40Cl2N2O3Ti
MW:
823.63
Product Categories:
  • Chiral Oxygen
  • TADDOL Series
Mol File:
197389-47-2.mol
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(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT Chemical Properties

form 
Powder
color 
yellow
Sensitive 
air sensitive, moisture sensitive
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Safety Information

Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36/37/39
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(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT Usage And Synthesis

Reaction

  1. Catalyst used in the enantioselective fluorination of β-ketoesters.
  2. Versatile catalyst used in the enantioselective 1,2 and 1,4 additions to carbonyl compounds, transfer of allyl groups to aldehydes, cycloadditions and others. 

(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCTSupplier

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