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2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

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2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Basic information

Product Name:
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Synonyms:
  • Isopropoxyboronic acid pinacol
  • Isopropoxyboronic acid picol ester
  • Isopropoxyboronic a
  • Isopropoxyboronic aci
  • 2-ISOPROPOXY-4,4,5,5-TETRAMETHYL-1,3,2-DIOABOROLANE
  • 2-Isopropoxyboronic acid, pinacol cyclic ester
  • sopropoxyboronic acid pinacol ester
  • Isopropoxyboronic acid pinacol ester 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS:
61676-62-8
MF:
C9H19BO3
MW:
186.06
EINECS:
612-189-2
Product Categories:
  • Boric Acid| Boric Acid Ester| Potassium Trifluoroborate
  • B (Classes of Boron Compounds)
  • Boric Acid Esters
  • Boric Acid Triesters
  • Boronic Acids and Derivatives
  • Organoborates
  • Boronic ester
  • Organoborons
  • Organometallic Reagents
  • Organic boronic acid
Mol File:
61676-62-8.mol
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2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Chemical Properties

Boiling point:
73 °C15 mm Hg(lit.)
Density 
0.912 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.409(lit.)
Flash point:
109 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid
Specific Gravity
0.912
color 
Colorless
Water Solubility 
Soluble in water.
Sensitive 
Moisture Sensitive
BRN 
1906370
InChI
InChI=1S/C9H19BO3/c1-7(2)11-10-12-8(3,4)9(5,6)13-10/h7H,1-6H3
InChIKey
MRWWWZLJWNIEEJ-UHFFFAOYSA-N
SMILES
O1C(C)(C)C(C)(C)OB1OC(C)C
CAS DataBase Reference
61676-62-8(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
10-36/37/38
Safety Statements 
16-26-36
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
HazardClass 
3
PackingGroup 
III
HS Code 
29209090

MSDS

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2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Usage And Synthesis

Chemical Properties

Colorless liquid

Uses

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane can be used as a reagent to borylate arenes and to prepare fluorenylborolane.

It can also be used in the synthesis of following intermediates for generating conjugated copolymers:

  • 9,9-Dioctyl-2,7-bis(4,4,5,5-tetramethyl1,3,2-dioxaborolane-2-yl)dibenzosilole.
  • 3,9-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5,11-di(1-decylundecyl)indolo[3,2-b]carbazole.
  • 2,7-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-dioctylfluorene.
  • 2,7-Bis(4′,4′,5′,5′-tetramethyl-1′,3′,2′-dioxaborolan-2′-yl)-N-9′′-heptadecanylcarbazole.

Uses

suzuki reaction

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolaneSupplier

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