P-TOLYL BENZOATE
P-TOLYL BENZOATE Basic information
- Product Name:
- P-TOLYL BENZOATE
- Synonyms:
-
- 4-cresylbenzoate
- Benzoic acid, 4-tolyl ester
- Benzoic acid, p-tolyl ester
- Benzoicacid,4-methylphenylester
- benzoicacid,p-tolylester
- p-cresolbenzoate
- p-Cresyl benzoate
- p-cresylbenzoate
- CAS:
- 614-34-6
- MF:
- C14H12O2
- MW:
- 212.24
- EINECS:
- 210-380-1
- Mol File:
- 614-34-6.mol
P-TOLYL BENZOATE Chemical Properties
- Melting point:
- 70-72 °C (lit.)
- Boiling point:
- 316°C (estimate)
- Density
- 1.1035 (rough estimate)
- refractive index
- 1.6000 (estimate)
- LogP
- 3.590
- EPA Substance Registry System
- p-Tolyl benzoate (614-34-6)
MSDS
- Language:English Provider:SigmaAldrich
P-TOLYL BENZOATE Usage And Synthesis
Chemical Properties
p-Tolyl Benzoate is a colorless or white plate crystals. M.P. 72℃. BP. 316℃. Insoluble in water, modestly soluble in alcohol, miscible with most perfume oils. Very faint odor, somewhat sweeter than that of para-Cresylsalicy late, more floral.
Uses
p-Tolyl Benzoate is rarely used in perfumes, occasionally as a fixative-modifier in Lily -Jasmin-Narcissus type bases.
Preparation
From para-Cresol sodium and Benzoyl chloride.
General Description
4-Methylphenyl benzoate is an ester. Structure of 4-methylphenyl benzoate resembles phenyl benzoate and 4-methoxy-phenyl benzoate, in terms of similar geometric parameters. The dihedral angle between the phenyl and benzene rings in 4-methylphenyl benzoate is 60.17 (7)°. Fries rearrangement of 4-methoxy-phenyl benzoate catalyzed by sulfated zirconia is reported.
Safety Profile
Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
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P-TOLYL BENZOATE(614-34-6)Related Product Information
- FUMARPROTOCETRARIC ACID
- EVERNIC ACID
- 4-CYANOPHENYL 4-N-BUTYLBENZOATE
- 4-tert-Butylphenyl Salicylate
- 4-CYANOPHENYL 4-HEPTYLBENZOATE
- P-TOLYL BENZOATE
- 4,4',4''-TRIS(BENZOYLOXY)TRITYL BROMIDE
- ATRANORIN
- SALICYLIC ACID 4-OCTYLPHENYL ESTER
- Estradiol benzoate
- 4-Pentylphenyl 4-propylbenzoate
- 4′-Methylbiphenyl-2-carboxylic acid methyl ester
- O-TOLYL BENZOATE
- 4-PENTYLPHENYL 2-CHLORO-4-(4-PENTYLBENZOYLOXY)BENZOATE
- STICTIC ACID
- (4-TERT-BUTYLPHENYL)BENZOATE
- 4-METHYLUMBELLIFERYL-P-GUANIDINOBENZOATE HYDROCHLORIDE
- 4-BENZOYLOXYBENZOIC ACID