(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL Basic information
- Product Name:
- (S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
- Synonyms:
-
- (S)-3,3'-DIBROMO-2,2'-DIHYDROXY-1,1'-BINAPHTHYL
- (S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
- (S)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
- (R)-3,3'-DIBROMO-2,2'-DIHYDROXY-1,1'-BINAPHTHYL
- (R)-(+)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
- (R)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
- 3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
- 3,3-DIBROMO-1,1'-BI-2-NAPHTHOL
- CAS:
- 119707-74-3
- MF:
- C20H12Br2O2
- MW:
- 444.12
- Product Categories:
-
- BINOL Series
- Chiral Oxygen
- chiral
- BINOLs
- Chiral Catalysts, Ligands, and Reagents
- Privileged Ligands and Complexes
- Asymmetric Synthesis
- Synthetic Organic Chemistry
- Mol File:
- 119707-74-3.mol
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(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL Chemical Properties
- Melting point:
- 256-260 °C
- alpha
- -40° (c 0.15, CHCl3)
- Boiling point:
- 469.9±40.0 °C(Predicted)
- Density
- 1.761±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- within almost transparency in Methanol
- pka
- 6.43±0.50(Predicted)
- form
- Powder
- color
- White to brown
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Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 36/37/38-22
- Safety Statements
- 26-36/37/39-37/39
- RIDADR
- UN 3077 9 / PGIII
- WGK Germany
- 3
- HS Code
- 29081990
MSDS
- Language:English Provider:SigmaAldrich
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(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL Usage And Synthesis
Reaction
- Ligand used to prepare a chiral zirconium catalyst useful in asymmetric Strecker reactions.
- Ligand used in the zinc-catalyzed enantioselective Hetero Diels-Alder reaction.
- Catalyst used in syn-selective diastereoselective Petasis reactions.
- Catalyst used in asymmetric propargylation of ketones.
Chemical Properties
white to light yellow crystal powde
General Description
(S)-(-)-3,3′-Dibromo-1,1′-bi-2-naphthol may be used as a catalyst in the preparation of (R)-1-(2-propenyl)-2-(3-phenoxymethoxypropyl)-2-cyclohexenol.
(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOLSupplier
Tianjin Derchemist Science & Technology Co., Ltd. Gold
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TCI (Shanghai) Development Co., Ltd.
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- 021-67121386
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(S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL(119707-74-3)Related Product Information
- 1,1'-Bi-2-naphthol
- (S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
- (S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
- (S)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol
- (S)-(-)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL
- (R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol
- (S)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL DIMETHYL ETHER,3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL DIMETHYL ETHER,(R)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL DIMETHYL ETHER
- (S)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL DIMETHYL ETHER,3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL DIMETHYL ETHER,(R)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL DIMETHYL ETHER
- (R)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL DIMETHYL ETHER,(S)-3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL DIMETHYL ETHER,3,3'-DIBROMO-1,1'-BI-2-NAPHTHOL DIMETHYL ETHER