Basic information Reactions Safety Supplier Related

(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol

Basic information Reactions Safety Supplier Related

(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol Basic information

Product Name:
(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol
Synonyms:
  • 6'-DIBROMO-1,1'-BI-2-NAPHTHOL
  • (+/-)-6,6'-DIBROMO-2,2'-DIHYDROXY-1,1'-BINAPHTHYL
  • (+/-)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
  • 6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
  • (R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol,min.98%
  • (R)-(-)-6,6''-DIBROMO-1,1''-BI-2-NAPHTOL
  • AURORA KA-7214
  • (S)-(+)-6'-DIBROMO-1,1'-BI-2-NAPHTHOL
CAS:
65283-60-5
MF:
C20H12Br2O2
MW:
444.12
Product Categories:
  • BINOL Series
  • Chiral Oxygen
  • Chiral Compound
  • BINOLs
  • Chiral Catalysts, Ligands, and Reagents
  • Privileged Ligands and Complexes
  • chiral
  • Asymmetric Synthesis
  • Synthetic Organic Chemistry
Mol File:
65283-60-5.mol
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(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol Chemical Properties

Melting point:
195-199 °C(lit.)
Boiling point:
546.2±45.0 °C(Predicted)
alpha 
-48 º (c=1.8, THF)
Density 
1.5428 (rough estimate)
refractive index 
1.4947 (estimate)
storage temp. 
Inert atmosphere,Room Temperature
Water Solubility 
Insoluble in water
form 
powder to crystal
pka
7.78±0.50(Predicted)
color 
White to Light yellow to Light orange
optical activity
[α]20/D 49°, c = 1.8 in acetic acid
CAS DataBase Reference
65283-60-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-22
Safety Statements 
26-36-37/39
WGK Germany 
3
HS Code 
29081990

MSDS

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(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol Usage And Synthesis

Reactions

  1. Ligand used to prepare a chiral zirconium catalyst useful in asymmetric Strecker and Mannich-type reactions.
  2. Ligand used for titanium-catalyzed enantioselective Friedel-Crafts reactions. 

Chemical Properties

white to light yellow crystal powde

(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphthol Preparation Products And Raw materials

Raw materials

(R)-(-)-6,6'-Dibromo-1,1'-bi-2-naphtholSupplier

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