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Ferrocenecarboxaldehyde

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Ferrocenecarboxaldehyde Basic information

Product Name:
Ferrocenecarboxaldehyde
Synonyms:
  • formyl-ferrocen
  • CYCLOPENTADIENYL(FORMYL-CYCLOPENTADIENYL)IRON
  • FERROCENEALDEHYDE
  • FERROCENECARBALDEHYDE
  • FERROCENECARBOXALDEHYDE
  • FORMYLFERROCENE
  • Ferrocenecarboxaldehyde,min.98%
  • Ferrocene, formyl-
CAS:
12093-10-6
MF:
C11H10FeO 10*
MW:
214.04
EINECS:
235-158-1
Product Categories:
  • Acylation Reagents
  • Electrochemical
  • Aldehydes
  • Analytical Reagents
  • Analytical/Chromatography
  • Building Blocks
  • C10-C12
  • Carbonyl Compounds
  • Chemical Synthesis
  • Derivatization Reagents
  • Derivatization Reagents HPLC
  • Organic Building Blocks
  • UV-VIS
  • Pyridines ,Heterocyclic Acids
  • metallocene
  • Aromatic Aldehydes & Derivatives (substituted)
  • Ferrocene series
Mol File:
12093-10-6.mol
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Ferrocenecarboxaldehyde Chemical Properties

Melting point:
118-120 °C(lit.)
form 
Crystalline Powder or Crystals or Crystals
color 
Orange to red to brown
Water Solubility 
INSOLUBLE
λmax
314nm(DMF aq.)(lit.)
Sensitive 
Air Sensitive
Stability:
Stable. Incompatible with strong oxidizing agents.
EPA Substance Registry System
Ferrocenecarboxaldehyde (12093-10-6)
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Safety Information

Safety Statements 
22-24/25
WGK Germany 
3
TSCA 
Yes
HS Code 
29319090

MSDS

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Ferrocenecarboxaldehyde Usage And Synthesis

Chemical Properties

crystalline solid

Purification Methods

It forms red crystals from heptane/CH2Cl2, EtOH or pet ether and sublimes at 70o/1mm. The cyanohydrin has m 104o (from *C6H6/EtOH). The semicarbazone has m 217-219o(dec) after recrystallisation from aqueous EtOH. The oxime provides two isomers from pet ether viz m 96-99o and m 155o. The O-acetyloxime has m 80-81o after recrystallisation from hexane [Lindsay & Hauser J Org Chem 22 355 1957]. The 2,4-dinitrophenylhydrazone has m 248o(dec). [Beilstein 16 IV 1798, Graham et al. J Am Chem Soc 79 3416 1957, Broadhead et al. J Chem Soc 650 1958.]

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