CROTYL BROMIDE TECH. 85 Chemical Properties

Melting point:

-115.07°C (estimate)

Boiling point:

97-99 °C(lit.)

Density 

1.312 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.480(lit.)

Flash point:

11 °C

storage temp. 

2-8°C

solubility 

soluble in Deuterated Chloroform ,Dichloroemthane, Hexanes

form 

Liquid

color 

Clear light yellow to yellow-brown

BRN 

1361394

InChIKey

AVMHMVJVHYGDOO-NSCUHMNNSA-N

EPA Substance Registry System

2-Butene, 1-bromo-, (2E)- (29576-14-5)

Safety Information

Hazard Codes 

F,Xi

Risk Statements 

11-36/37-36/37/38

Safety Statements 

16-26-27-36/37/39-37/39

RIDADR 

1993

WGK Germany 

3

HazardClass 

3.1

PackingGroup 

II

HS Code 

29033990

CROTYL BROMIDE TECH. 85 Usage And Synthesis

Chemical Properties

clear light yellow to yellow-brown liquid

Uses

Crotyl bromide is a general organic reagent that can be used in the total synthesis of biologically important natural products and their derivatives such as (+)-artemisinin, plakortone E and (?)-horsfiline.
It can also be used to prepare analogs of deoxycyclitols, pentopyranoses, 6-deoxyhexoses, hexoses and pseudo-indoxyl derivatives.

Purification Methods

Dry the bromide with MgSO4/CaCO3 mixture and fractionally distil it through an all-glass Todd column (p 11). [Beilstein 1 IV 789.]

CROTYL BROMIDE TECH. 85(29576-14-5)Related Product Information

• TRANS-2-BROMO-2-BUTENE,2-BROMO-2-BUTENE,CIS,TRANS-2-BROMO-2-BUTENE,(E)-2-BROMO-2-BUTENE,(E)-2-BROMO-2-BUTENE 96%
• 1-Bromo-3-butene,4-BROMO-1-BUTENE, STAB.,4-Bromo-1-butene, 98+%,4-Bromo-1-butene, GC 98%
• 2-BROMO-1-BUTENE
• 3-Methyl-1-bromo-2-buten
• (2E)-1-Bromo-2-butene,4-bromo-2-buten
• 3,3,4,4-Tetrafluoro-4-bromo-1-butene
• aceticacid,bromo-,2-butene-1,4-diyleste
• 2-BROMO-2-BUTENE
• 3-BUTENYLMAGNESIUM BROMIDE
• CIS-2-BROMO-2-BUTENE,(Z)-2-BROMO-2-BUTENE,(Z)-2-BROMO-2-BUTENE 97%
• 3,4,4-Trifluoro-1-bromo-3-butene,1,1,2-Trifluoro-4-bromo-1-butene
• (Z)-1-Bromo-2-butene,(2Z)-1-Bromo-2-butene
• 3-BROMO-1-BUTENE
• cis-bromo-1-buten
• 4-(2-ACETOXYPHENYL)-2-BROMO-1-BUTENE
• TRANS-1-BROMO-1-BUTENE,1-BROMO-1-BUTENE,1-BROMO-1-BUTENE MIXTURE OF ISOMERS
• 4-(4-ACETOXYPHENYL)-2-BROMO-1-BUTENE
• 4-(3-ACETOXYPHENYL)-2-BROMO-1-BUTENE