Basic information Safety Supplier Related

5-Chloromethylfurfural

Basic information Safety Supplier Related

5-Chloromethylfurfural Basic information

Product Name:
5-Chloromethylfurfural
Synonyms:
  • 5-(chloromethyl)-2-furaldehyde
  • 5-(CHLOROMETHYL)FURFURAL
  • 5-(Chloromethyl)furan-2-carbaldehyde
  • 2-ForMyl-5-chloroMethylfuran
  • 5-(ChloroMethyl)-2-furfural
  • 5-(ChloroMethyl)furfuraldehyde
  • 2-[5-(chloromethyl)-2-furanyl]acetaldehyde
  • 2-Furancarboxaldehyde, 5-(chloromethyl)-
CAS:
1623-88-7
MF:
C6H5ClO2
MW:
144.56
EINECS:
216-608-6
Product Categories:
  • Furans
  • Aromatics
  • Heterocycles
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
Mol File:
1623-88-7.mol
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5-Chloromethylfurfural Chemical Properties

Melting point:
37 °C
Boiling point:
137-138 °C(Press: 5 Torr)
Density 
1.295±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
Dark Brown to Black Oil to Semi-Solid
Stability:
Moisture Sensitive
EPA Substance Registry System
2-Furancarboxyaldehyde, 5-(chloromethyl)- (1623-88-7)
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Safety Information

HS Code 
2932190090
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5-Chloromethylfurfural Usage And Synthesis

Chemical Properties

Dark Brown Oil

Uses

5-(Chloromethyl)furfural is a lipid oxidation product derived from soybean phospholipids. It is a biofuel precursor in the co-processing of carbohydrates and lipids in oil crops for production of hybrid biodiesel.

Application

5-Chloromethylfurfural is a biofuel that can be made from the reaction of hydrochloric acid and furfural. It is used as a feedstock for the production of 5-hydroxymethylfurfural, which is an important intermediate in the synthesis of many other chemicals. 5-Chloromethylfurfural has been isolated at a yield of 57% from reactions between furfural and chlorine gas. The use of solid catalysts have improved this yield to 68%. It has high chemical stability and can withstand temperatures up to 200°C without decomposition. It also reacts with fatty acids to form amides.

Synthesis Reference(s)

Synthesis, p. 541, 1992 DOI: 10.1055/s-1992-26158

General Description

5-(Chloromethyl) Furfural (CMF) is a potential chemical building block for replacing petroleum-derived chemicals derived from lignocellulosic feedstocks. It is gaining traction as a more practical alternative to 5-(hydroxymethyl)furfural (HMF).

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