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2-Hydroxy-1-naphthaldehyde

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2-Hydroxy-1-naphthaldehyde Basic information

Product Name:
2-Hydroxy-1-naphthaldehyde
Synonyms:
  • 2-Hydroxy-1-phthaldehyde
  • 1-formyl-2-hydroxynaphthalene
  • 1-Formyl-2-hydroxy-naphthalene
  • 1-Formyl-2-naphthol
  • 1-Hydroxy-2-naphthalenecarboxaldehyde
  • 1-Naphthaldehyde, 2-hydroxy-
  • 2-Hydroxy-1-naphthalaldehyde
  • 2-hydroxy-1-naphthaldehyd
CAS:
708-06-5
MF:
C11H8O2
MW:
172.18
EINECS:
211-902-0
Product Categories:
  • Naphthalene series
  • Building Blocks
  • C10-C12
  • Carbonyl Compounds
  • Chemical Synthesis
  • Organic Building Blocks
  • Intermediates of Dyes and Pigments
  • Aromatic Aldehydes & Derivatives (substituted)
  • Aldehydes
  • C10 to C21
  • Carbonyl Compounds
Mol File:
708-06-5.mol
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2-Hydroxy-1-naphthaldehyde Chemical Properties

Melting point:
76-80 °C (lit.)
Boiling point:
192 °C/27 mmHg (lit.)
Density 
1.1153 (rough estimate)
vapor pressure 
0.002Pa at 20℃
refractive index 
1.5500 (estimate)
Flash point:
191-193°C/27mm
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform, Methanol
form 
Crystalline Moist Powder
pka
8.27±0.50(Predicted)
color 
Yellow
Water Solubility 
Soluble in water (40 g/L at 20°C).
Sensitive 
Air Sensitive
BRN 
742777
LogP
6 at 23℃ and pH8
CAS DataBase Reference
708-06-5(CAS DataBase Reference)
NIST Chemistry Reference
1-Naphthalenecarboxaldehyde, 2-hydroxy-(708-06-5)
EPA Substance Registry System
1-Naphthalenecarboxaldehyde, 2-hydroxy- (708-06-5)
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Safety Information

Hazard Codes 
Xi,N
Risk Statements 
36/37/38-50/53
Safety Statements 
26-36-60-61-24/25-37
RIDADR 
UN 3077 9/PG 3
WGK Germany 
2
RTECS 
QJ0300000
TSCA 
Yes
HazardClass 
9
HS Code 
29124990

MSDS

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2-Hydroxy-1-naphthaldehyde Usage And Synthesis

Chemical Properties

Powder

Uses

2-Hydroxy-1-naphthaldehyde is used in Merrified-type synthesis to deterime free amino acid groups in polymers.

Definition

ChEBI: 2-hydroxy-1-naphthaldehyde is a member of the class of naphthaldehydes that is naphthalene-1-carbaldehyde substituted by a hydroxy group at position 2. Active core of sirtinol (CHEBI:73158). It is a member of naphthaldehydes and a member of naphthols.

Purification Methods

Crystallise the aldehyde from EtOH (1.5mL/g), aqueous EtOH, aqueous AcOH (m 84o), EtOAc or H2O. [Russell & Lockhart Org Synth Coll Vol III 463 1955, Beilstein 8 H 143, 8 I 564, 8 II 171, 8 III 1108, 8 IV 1160.]

2-Hydroxy-1-naphthaldehyde Preparation Products And Raw materials

Raw materials

Preparation Products

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