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Silica glass

Basic information Structure Safety Supplier Related

Silica glass Basic information

Product Name:
Silica glass
Synonyms:
  • LUDOX(R) TMA COLLOIDAL SILICA
  • LUDOX(R) AM-30 COLLOIDAL SILICA
  • LUDOX(R) AS-30 COLLOIDAL SILICA
  • LUDOX(R) AS-40 COLLOIDAL SILICA
  • LUDOX(R) CL COLLOIDAL SILICA
  • LUDOX(R) CL-X COLLOIDAL SILICA
  • LUDOX(R) HS-30 COLLOIDAL SILICA
  • LUDOX(R) HS-40 COLLODIAL SILICA
CAS:
10279-57-9
MF:
H2O3Si
MW:
78.1
EINECS:
600-358-3
Product Categories:
  • Silicone Series
  • Inorganics
  • photoazide
Mol File:
10279-57-9.mol
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Silica glass Chemical Properties

Melting point:
1610 °C(lit.)
Boiling point:
>100 °C(lit.)
Density 
2.6 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.544(lit.)
storage temp. 
no restrictions.
form 
tablets (~0.5 g each)
Water Solubility 
Insoluble in water.
Exposure limits
NIOSH: IDLH 3000 mg/m3; TWA 6 mg/m3
InChI
InChI=1S/O2Si.H2O/c1-3-2;/h;1H2
InChIKey
LRCFXGAMWKDGLA-UHFFFAOYSA-N
SMILES
[Si](=O)=O.O
EPA Substance Registry System
Silica, hydrate (10279-57-9)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
48/20
Safety Statements 
22
WGK Germany 
3
RTECS 
VV7340000
3
HS Code 
2811 22 00
Toxicity
LD50 orally in Rabbit: > 10000 mg/kg LD50 dermal Rabbit > 5000 mg/kg

MSDS

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Silica glass Usage And Synthesis

Structure

Silica glass is a continuous network of corner-sharing SiO4 tetrahedra where each oxygen bridges two tetrahedra (i.e. only Q4 speciation). However, a more complex system might contain 75% Q3 (tetrahedra with one free non-bridging oxygen) and 25% Q2 (two non-bridging oxygens). For silica glasses, the first diffraction peak, Q1, has been associated with intermediate-range ordering with a periodicity of 2π/Q1 ~ 6 Å. This ordering beyond the first few nearest neighbour tetrahedra arises from the boundaries between successions of cages comprising a 3-D covalent network structure. Therefore, the position and shape of the first sharp diffraction peak Q1 can provide information on different-sized ring distributions within the material. The second diffraction peak at position Q2 has been linked to chemical or extended range ordering with a periodicity of 2π/Q2 ~ 3 Å, and the local Si–O–Si and O–Si–O bond-angle distributions can persist to distances as large as > 5 Å.

Uses

Typical properties: S.A.250m^2/gSilicon oxide is used as a catalyst support material having a high surface area. It acts as a medium to which catalyst is affixed. Several metals such as platinum, rhodium, ruthenium, silver, copper, nickel, iron, manganese, cobalt, tungsten and gold are supported over silicon dioxide and used as a catalyst in synthetic chemistry for various applications. For example, silica-supported gold catalysts is used for carbon monoxide oxidation by a solution-based technique.

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