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(4-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE

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(4-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE Basic information

Product Name:
(4-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE
Synonyms:
  • (p-nitrobenzyl)triphenyl-phosphoniubromide
  • (P-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE
  • TRIPHENYL(4-NITROBENZYL)PHOSPHONIUM BROMIDE
  • (4-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE
  • Bromo[(4-nitrophenyl)methyl]triphenylphosphorane
  • NSC 104840
  • NSC 617038
  • (4-Nitrobenzyl)triphenylphosphonium bromide 97%
CAS:
2767-70-6
MF:
C25H21BrNO2P
MW:
478.32
EINECS:
220-444-0
Product Categories:
  • Phosphonium Compounds
  • Synthetic Organic Chemistry
  • Wittig & Horner-Emmons Reaction
  • Wittig Reaction
  • C-C Bond Formation
  • Olefination
  • Wittig Reagents
Mol File:
2767-70-6.mol
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(4-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE Chemical Properties

Melting point:
275 °C (dec.)(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in Methanol
form 
solid
color 
White to Almost white
CAS DataBase Reference
2767-70-6(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37
WGK Germany 
3
RTECS 
TA2390000
HS Code 
29319000
Toxicity
mouse,LD50,intravenous,18mg/kg (18mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#00884,

MSDS

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(4-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE Usage And Synthesis

Chemical Properties

white to light yellow powder

Uses

(4-Nitrobenzyl)triphenylphosphonium Bromide acts as a reagent in the preparation of substituted benzyl triphenyl phosphonium halides as antibacterial agents by quaternization of triphenylphosphine with benzyl halides.

Uses

Reactant for the synthesis of:

  • PPAR agonists derived from LXR antagonists
  • Stilbene derivatives for use in detection of nerve agents and for attaching to polymers to elicit fluorescent behavior
  • Distyrylfurans
  • Pyrethoids with insecticidal activity
  • Pyridinylidene amines with antimalarial activity

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