(4-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE Chemical Properties

Melting point:

275 °C (dec.)(lit.)

storage temp. 

Inert atmosphere,Room Temperature

solubility 

soluble in Methanol

pka

20.1(Solvent: 1-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide)

form 

solid

color 

White to Almost white

InChI

1S/C25H21NO2P.BrH/c27-26(28)22-18-16-21(17-19-22)20-29(23-10-4-1-5-11-23,24-12-6-2-7-13-24)25-14-8-3-9-15-25;/h1-19H,20H2;1H/q+1;/p-1

InChIKey

IPJPTPFIJLFWLP-UHFFFAOYSA-M

SMILES

[Br-].[O-][N+](=O)c1ccc(C[P+](c2ccccc2)(c3ccccc3)c4ccccc4)cc1

CAS DataBase Reference

2767-70-6(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36-37

WGK Germany 

3

RTECS 

TA2390000

HS Code 

29319000

Storage Class

11 - Combustible Solids

Hazard Classifications

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

Toxicity

mouse,LD50,intravenous,18mg/kg (18mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#00884,

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

(4-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE Usage And Synthesis

Chemical Properties

white to light yellow powder

Uses

(4-Nitrobenzyl)triphenylphosphonium Bromide acts as a reagent in the preparation of substituted benzyl triphenyl phosphonium halides as antibacterial agents by quaternization of triphenylphosphine with benzyl halides.

Uses

Reactant for the synthesis of:

• PPAR agonists derived from LXR antagonists
• Stilbene derivatives for use in detection of nerve agents and for attaching to polymers to elicit fluorescent behavior
• Distyrylfurans
• Pyrethoids with insecticidal activity
• Pyridinylidene amines with antimalarial activity

reaction suitability

reaction type: C-C Bond Formation

(4-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE(2767-70-6)Related Product Information

• Benzotriazole-1-yl-oxytripyrrolidinophosphonium hexafluorophosphate
• (2-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE MONOHYDRATE
• Benzyltriphenylphosphonium hydroxide
• (4-NITROBENZYL)TRIPHENYLPHOSPHONIUM BROMIDE
• Benzyltriphenylphosphonium bromide
• BENZYL TRIPHENYL PHOSPHONIUM HYDROXIDE