THALLIC ACETATE
THALLIC ACETATE Basic information
- Product Name:
- THALLIC ACETATE
- Synonyms:
-
- THALLIC ACETATE
- THALLIUM ACETATE (IC)
- THALLIUM (IC) ACETATE SESQUIHYDRATE
- THALLIUM(III) ACETATE
- ACETIC ACID, THALLIC SALT SESQUIHYDRATE
- ACETIC ACID, THALLIUM(III) SALT
- aceticacid,thallium(3++)salt
- Thallium(III) acetate, 98.6%
- CAS:
- 2570-63-0
- MF:
- C2H5O2Tl
- MW:
- 265.44
- EINECS:
- 219-913-2
- Product Categories:
-
- Catalysis and Inorganic Chemistry
- Chemical Synthesis
- Thallium
- Mol File:
- 2570-63-0.mol
THALLIC ACETATE Chemical Properties
- Melting point:
- 182 °C (dec.)(lit.)
- storage temp.
- Poison room
- solubility
- sol hot acetic acid, alcohols, H2O.
- form
- Crystalline Powder
- color
- White to off-white
- BRN
- 3693590
- CAS DataBase Reference
- 2570-63-0(CAS DataBase Reference)
- EPA Substance Registry System
- Acetic acid, thallium(3+) salt (2570-63-0)
Safety Information
- Hazard Codes
- T+,N
- Risk Statements
- 26/28-33-51/53-26/27/28
- Safety Statements
- 13-28-45-61-36/37/39-22
- RIDADR
- UN 1707 6.1/PG 2
- WGK Germany
- 3
- HazardClass
- 6.1
- PackingGroup
- II
- HS Code
- 29152900
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
THALLIC ACETATE Usage And Synthesis
Chemical Properties
white to off-white crystalline powder
Uses
Thallium(III) Acetate is used for oxidation of alkenes and alkynes; oxidation of conjugated dienes; hydroxylation of double bonds; cleavage of cyclopropane rings; oxidation of enamines; oxidative rearrangements; bromination of aromatic compounds; oxidation of thiols and p-toluenesulfonylhydrazones; formation of acyloxy carboxylic acids; oxidative cyclizations.
Preparation
Thallium(III) Acetate can also be prepared by dissolving thallium(III) oxide in acetic acid and acetic anhydride and stirring at 80-90 °C. The solution is filtered, cooled and the product obtained is recrystallized.
reaction suitability
core: thallium
reagent type: catalyst
storage
Thallium(III) Acetate remains stable for long periods if kept in a well-sealed desiccator and away from light. It is extremely poisonous. Use in a fume hood.
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THALLIC ACETATE(2570-63-0)Related Product Information
- tert-Butyl methyl ether
- COPPER(II) ACETATE MONOHYDRATE
- YTTRIUM(III) ACETATE HYDRATE
- IridiuM acetate
- THALLIUM
- THALLIUM(III) TRIFLUOROACETATE
- THALLIC ACETATE
- THALLIUM(I) FORMATE
- THALLIUM(I) NITRATE
- THALLIUM(I) ACETATE
- THALLIUM (OUS) HYDROXIDE
- THALLIC ACETATE SESQUIHYDRATE,Thallic acetate sesquihydrate, 99.90%
- THALLIUM (I) ETHOXIDE
- THALLIUM(I) CHLORIDE
- THALLIUM(I) FLUORIDE
- THALLIUM(I) BROMIDE
- THALLIUM(I) 2,4-PENTANEDIONATE
- THALLIUM HEXAFLUOROPHOSPHATE