2,4,6-Triallyloxy-1,3,5-triazi Chemical Properties

Melting point:

26-28 °C

Boiling point:

156 °C

Density 

1.11 g/mL at 30 °C

vapor pressure 

1.3 hPa (100 °C)

refractive index 

1.5290 (estimate)

Flash point:

>230 °F

storage temp. 

Store at <= 20°C.

solubility 

0.3g/l

pka

2.04±0.10(Predicted)

form 

Oil

color 

Colourless

Specific Gravity

1.11

Water Solubility 

6g/L(20 ºC)

BRN 

235560

Stability:

Stable, but moisture-sensitive. Incompatible with acids, peroxides, strong oxidizing agents, copper, iron and its salts.

LogP

3.51 at 20℃

CAS DataBase Reference

101-37-1(CAS DataBase Reference)

NIST Chemistry Reference

2,4,6-Triallyloxy-1,3,5-triazine(101-37-1)

EPA Substance Registry System

1,3,5-Triazine, 2,4,6-tris(2-propenyloxy)- (101-37-1)

Safety Information

Hazard Codes 

Xn,N

Risk Statements 

22-51/53

Safety Statements 

36-61

RIDADR 

UN 3077 9/PG 3

WGK Germany 

2

RTECS 

XZ2080000

F 

21

TSCA 

Yes

HS Code 

2933 69 80

HazardClass 

6.1(b)

PackingGroup 

III

Toxicity

LD50 orally in Rabbit: 753 mg/kg LD50 dermal Rabbit > 2000 mg/kg

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

2,4,6-Triallyloxy-1,3,5-triazi Usage And Synthesis

Chemical Properties

Colorless liquid or solid. Miscible with acetone, benzene, chloroform, dioxane, ethyl acetate, ethanol, and xylene. Combustible.

Uses

Polymers as monomer and modifier, organic intermediate. Triallyl Cyanurate is used preferentially as a cross-linking agent in copolymers. On heating it may polymerize violently and then isomerize to the more stable triallyl isocyanurate [1025-15-6] with the allyl groups attached to the nitrogen atoms.
At 30 ℃ viscous solutions of prepolymers form slowly. Triallyl cyanurate is used for the production of heat- and solvent-resistant coatings and moldings, reinforced plastics, and adhesives. Addition of 5 – 10% triallyl cyanurate to polyester – styrene or methyl methacrylate yields cast sheets of improved mechanical and thermal stability. Short-term heating of triallyl cyanurate with polymers in the presence of peroxides at 180 ℃ gives cross-linking; valuable copolymers are thus obtained from poly(vinyl chloride) elastomers and fluoroelastomers. Ethylene polymers and copolymers also may be crosslinked under similar reaction conditions. High-impact plastics have been obtained by grafting butyl acrylate-triallyl cyanurate copolymer with a styrene – acrylonitrile mixture. Other examples of peroxide-initiated curing with triallyl cyanurate (2 – 5 %) at 150 – 160 ℃ are polyurethanes, nylons, cellulose, polyoxyethylene, vinyl-substituted polysiloxanes, and acrylate copolymers. Crosslinking of polycarbonate with triallyl cyanurate by UV irradiation in the presence of polythiols gives scratch-resistant coatings.

Definition

ChEBI: 2,4,6-triallyloxy-1,3,5-triazine is a member of 1,3,5-triazines and an aromatic ether.

Hazard

Toxic by ingestion and inhalation.

Flammability and Explosibility

Non flammable

Safety Profile

Poison by intravenous route. Flammable when exposed to heat, flame, or oxidizers. To fight fire, use spray, foam, dry chemical. When heated to decomposition or on contact with acid or acid fumes it emits hghly toxic fumes of CNand NOx. See also ESTERS and ALLYL, COMPOUNDS.

2,4,6-Triallyloxy-1,3,5-triazi(101-37-1)Related Product Information

• Allicin
• Cyanuric acid
• Allyl ether
• 2,4,6-TRIMETHOXY-1,3,5-TRIAZINE
• 1,3,5-Triazine
• ISOCYANURIC ACID DIALLYL ESTER
• 2,4,6-Triallyloxy-1,3,5-triazi