2,7-Dibromofluorene Chemical Properties

Melting point:

164-166 °C (lit.)

Boiling point:

329.77°C (rough estimate)

Density 

1.7203 (estimate)

refractive index 

1.6000 (estimate)

storage temp. 

Sealed in dry,Room Temperature

solubility 

Chloroform (Slightly)

form 

Crystalline Powder

color 

White to off-white

BRN 

2049205

InChI

InChI=1S/C13H8Br2/c14-10-1-3-12-8(6-10)5-9-7-11(15)2-4-13(9)12/h1-4,6-7H,5H2

InChIKey

AVXFJPFSWLMKSG-UHFFFAOYSA-N

SMILES

C1C2=C(C=CC(Br)=C2)C2=C1C=C(Br)C=C2

CAS DataBase Reference

16433-88-8(CAS DataBase Reference)

NIST Chemistry Reference

9H-fluorene, 2,7-dibromo-(16433-88-8)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-37/39

WGK Germany 

3

TSCA 

T

HazardClass 

IRRITANT

HS Code 

29420000

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

2,7-Dibromofluorene Usage And Synthesis

Description

2,7-Dibromofluorene is a halogenated polycyclic aromatic compound and its vapour pressure has been measured using the Knudsen effusion method.

Chemical Properties

white to off-white crystalline powder

Uses

2,7-Dibromofluorene was used as a template for the N-carbazole capped oligofluorenes which show potential as hole-transporting materials for organic light emitting devices (OLEDs). It may be used in the synthesis of conjugated polymer, poly[9,9′-bis(6′′-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), used in label-free DNA microarrays. It was used in the preparartion of blue photoluminescent unsymmetrically substituted polyfluorene. It was also used in the preparation of 2,7-dibromofluorene monomers containing benzyl ether dendrons (generations 1, 2 and 3) in the 9,9′-position of the fluorene ring, such as:
9,9-bis[(3,5-bis(benzyloxy)benzyloxy)methyl]-2,7-dibromofluorene
9,9-bis[(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy)-methyl] 2,7-dibromo-fluorene
9,9-bis[(3,5-bis(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy) benzyloxy)-methyl]-2,7-dibromofluorene

Uses

2,7-Dibromofluorene is used as a template for the N-carbazole capped oligofluorenes which show potential as hole-transporting materials for organic light emitting devices (OLEDs). It is also used in the synthesis of conjugated polymer, poly[9,9?-bis(6??-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), used in label-free DNA microarrays, in the preparation of blue photoluminescent unsymmetrically substituted polyfluorene and in the preparation of 2,7-dibromofluorene monomers containing benzyl ether dendrons (generations 1, 2 and 3) in the 9,9?-position of the fluorene ring, such as: 9,9-bis[(3,5-bis(benzyloxy)benzyloxy)methyl]-2,7-dibromofluorene, 9,9-bis[(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy)-methyl] 2,7-dibromo-fluorene, 9,9-bis[(3,5-bis(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy) benzyloxy)-methyl]-2,7-dibromofluorene.

Uses

2,7-Dibromofluorene was used as a template for the N-carbazole capped oligofluorenes which show potential as hole-transporting materials for organic light emitting devices (OLEDs). It may be used in the synthesis of conjugated polymer, poly[9,9′-bis(6′′-N,N,N-trimethylammonium)hexyl)fluorene-co-alt-4,7-(2,1,3-benzothiadiazole) dibromide] (PFBT), used in label-free DNA microarrays. It was used in the preparartion of blue photoluminescent unsymmetrically substituted polyfluorene. It was also used in the preparation of 2,7-dibromofluorene monomers containing benzyl ether dendrons (generations 1, 2 and 3) in the 9,9′-position of the fluorene ring, such as:

• 9,9-bis[(3,5-bis(benzyloxy)benzyloxy)methyl]-2,7-dibromofluorene
• 9,9-bis[(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy)-methyl] 2,7-dibromo-fluorene
• 9,9-bis[(3,5-bis(3,5-bis(3,5-bis(benzyloxy)benzyloxy)benzyloxy) benzyloxy)-methyl]-2,7-dibromofluorene

Synthesis

General procedure for the synthesis of 2,7-dibromofluorene from fluorene: Fluorene (1.5 g, 9.0 mmol) was dissolved in carbon tetrachloride (80 mL), followed by the addition of 30 g of copper(II) bromide loaded on aluminum oxide. The reaction mixture was stirred under reflux conditions for 5 hours. Upon completion of the reaction, the solution was cooled to room temperature, filtered to remove solid impurities, and the filter cake was washed with carbon tetrachloride (50 mL). The combined organic phases were dried with anhydrous magnesium sulfate. The solvent was removed by concentration under reduced pressure to give 2.87 g (98% yield) of 2,7-dibromofluorene as a yellow solid. Recrystallization by ethyl acetate/hexane (5:95, v/v) mixed solvent gave pure 2,7-dibromofluorene as light yellow crystals.

References

[1] Tetrahedron, 2003, vol. 59, # 17, p. 3131 - 3156
[2] Dyes and Pigments, 2015, vol. 113, p. 682 - 691
[3] Organic and Biomolecular Chemistry, 2018, vol. 16, # 22, p. 4071 - 4075
[4] Chemistry Letters, 2013, vol. 42, # 11, p. 1355 - 1357
[5] Bulletin of the Chemical Society of Japan, 1989, vol. 62, # 2, p. 439 - 443

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