LYCOPSAMINE
LYCOPSAMINE Basic information
- Product Name:
- LYCOPSAMINE
- Synonyms:
-
- LYCOPSAMINE
- (2S,3S)-2,3-Dihydroxy-2-isopropylbutanoic acid [(1R,7aR)-2,3,5,7a-tetrahydro-1-hydroxy-1H-pyrrolizine-7-yl]methyl ester
- (2S,3S)-2,3-Dihydroxy-2-isopropylbutanoic acid [(7R)-7β-hydroxy-5,6,7,7aα-tetrahydro-3H-pyrrolizine-1-yl]methyl ester
- (1R-(1alpha,7(2S*,3S*),7Abeta))-(2,3,5,7A-tetrahydro-1-hydroxy-1H-pyrrolizin-7-yl)methyl 2,3-dihydroxy-2-(1-methylethyl)butanoate
- Butanoic acid, 2,3-dihydroxy-2-(1-methylethyl)-, ((1R,7ar)-2,3,5,7A-tetrahydro-1-hydroxy-1H-pyrrolizin-7-yl)methyl ester, (2S,3S)-
- Butanoic acid, 2,3-dihydroxy-2-(1-methylethyl)-, (2,3,5,7A-tetrahydro-1-hydroxy-1H-pyrrolizin-7-yl)methyl ester, (1R-(1alpha,7(2S*,3S*),7abeta))-
- Ccirs 9199
- Ccris 9199
- CAS:
- 10285-07-1
- MF:
- C15H25NO5
- MW:
- 299.36
- Product Categories:
-
- Amines, Heterocycles
- Mol File:
- 10285-07-1.mol
LYCOPSAMINE Chemical Properties
- Melting point:
- 41-44°C
- Boiling point:
- 463.3±45.0 °C(Predicted)
- Density
- 1.26±0.1 g/cm3 (20 ºC 760 Torr)
- storage temp.
- -20°C
- solubility
- Chloroform, Ethanol
- pka
- 12.59±0.29(Predicted)
- form
- Solid
- color
- Off-White
LYCOPSAMINE Usage And Synthesis
Description
This amorphous pyrrolizidine alkaloid has been isolated from Arnsinckia hispida (Ruiz et Pav.) Johnst., A. interrnedia Fisch & Mey, and A. lycopsoides Lehm. It is dextrorotatory having [α]20D + 3.1 ° (c 5.98, EtOH). Alkaline hydrolysis yields retronecine and viridifloric acid.
Uses
(+)-Lycopsamine, occurs in pyrrolizidine alkaloid-containing plants, which are the most common poisonous plants affecting livestock, wildlife, and humans. Thye are being known as hepatotoxins and tumorigens.It has been shown that pyrrolizidine Alkaloid-Derived DNA Adducts, are the common biological biomarker of pyrrolizidine alkaloid-induced liver tumor formation.
Definition
ChEBI: Lycopsamine is a member of pyrrolizines.
General Description
This substance is a primary reference substance with assigned absolute purity (considering chromatographic purity, water, residual solvents, inorganic impurities). The exact value can be found on the certificate. Produced by PhytoLab GmbH & Co. KG
References
Cu1venor, Smith., Austral. 1. Chern., 19, 1955 (1966)
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