9-Bromophenanthrene
9-Bromophenanthrene Basic information
- Product Name:
- 9-Bromophenanthrene
- Synonyms:
-
- 9-BROMOPHENANTHRENE
- 9-Bromophenathrene
- 9-Bromophenanthrene,95%
- 9-Bromophenanthrene,97%
- Phenanthrene, 9-bromo-
- 9-Bromoanth raceme 96%
- 9-Bromophenanthrene,96%
- 9-BroMophenanthrene, 96% 10GR
- CAS:
- 573-17-1
- MF:
- C14H9Br
- MW:
- 257.13
- EINECS:
- 209-351-6
- Product Categories:
-
- blocks
- Bromides
- Miscellaneous
- Aryl
- C13 to C37+
- Halogenated Hydrocarbons
- Aromatic Compounds
- Mol File:
- 573-17-1.mol
9-Bromophenanthrene Chemical Properties
- Melting point:
- 60-64 °C(lit.)
- Boiling point:
- 180-190 °C2 mm Hg(lit.)
- Density
- 1.4251 (rough estimate)
- refractive index
- 1.6404 (estimate)
- Flash point:
- >230 °F
- storage temp.
- Store below +30°C.
- solubility
- chloroform: 50 mg/mL, clear
- form
- Powder
- color
- Light yellow
- BRN
- 1869927
- InChIKey
- RSQXKVWKJVUZDG-UHFFFAOYSA-N
- CAS DataBase Reference
- 573-17-1(CAS DataBase Reference)
- NIST Chemistry Reference
- Phenanthrene, 9-bromo-(573-17-1)
Safety Information
- Hazard Codes
- Xi,Xn
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 22-24/25-36-26
- WGK Germany
- 3
- RTECS
- SF7197000
- F
- 8
- Hazard Note
- Irritant
- HS Code
- 29036990
MSDS
- Language:English Provider:9-Bromophenanthrene
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
9-Bromophenanthrene Usage And Synthesis
Chemical Properties
light yellow powder
Uses
9-Bromophenanthrene is used as halogenated building block. Isotope labelled 9-Bromophenanthrene (B687200), a halogenated polycyclic aromatic hydrocarbon that has been seen to have a room temperature phosphorescence that can be induced by β-cyclodextrin (β-CD) in the presence of cyclohexane; however, trace Fe(III) causes a decrease of the RTP emission.
Preparation
9-Bromophenanthrene (90-94%) is produced by adding bromine to a refluxing solution of phenanthrene in carbon tetrachloride. This is the starting-point of 9-substituted phenanthrenes, e.g, when heated with cuprous cyanide at 260℃, 9-bromophenanthrene forms the corresponding cyano-compound; this may be hydrolysed to phenanthrene-9-carboxylic acid. Phenanthrene undergoes the Friedel-Crafts reaction mainly in the 3-, and to a small extent, in the 2-position. It is chloromethylated in the 9-position. When nitrated, phenanthrene gives a mixture of three mononitro-derivatives, the 3-isomer predominating. Sulphonation of phenanthrene gives a mixture of 1-, 2-, 3- and 9-phenanthrenesulphonic acids, and the ratio of these isomers depends on the temperature.
9-Bromophenanthrene Preparation Products And Raw materials
Raw materials
Preparation Products
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9-Bromophenanthrene(573-17-1)Related Product Information
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- (3-BROMO-2,4,6-TRIMETHYLPHENYLCARBAMOYL)METHYLIMINODIACETIC ACID
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