2-NAPHTHYL TRIFLATE Chemical Properties

Melting point:

30-32 °C(lit.)

Boiling point:

87°C/0.2mmHg(lit.)

Density 

1.493±0.06 g/cm3(Predicted)

Flash point:

>230 °F

storage temp. 

Sealed in dry,Room Temperature

form 

Solid

color 

White to orange

Safety Information

Hazard Codes 

C

Risk Statements 

34

Safety Statements 

22-26-27-36/37/39-45

RIDADR 

UN 3261 8/PG 2

WGK Germany 

3

HazardClass 

8

HS Code 

29049090

MSDS

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2-NAPHTHYL TRIFLATE Usage And Synthesis

Uses

2-Naphthyl trifluoromethanesulfonate (2-naphthyl triflate) may be used as an arylating agent in the arylation of 1-(methoxycarbonyl)-2,5-dihydropyrrole by Heck reaction. It may be used as a substrate for coupling with Reformatsky reagent BrZnCH(CH₃)(COO^tC₄H₉) in the presence of “reduced” dichlorobis(1,1-diphenylphosphino)ferrocene catalyst.

General Description

2-Naphthyl trifluoromethanesulfonate (2-naphthyl triflate) is an aryl triflate. Its ruthenium-catalyzed conversion to 2-bromonaphthalene has been reported.

2-NAPHTHYL TRIFLATE(3857-83-8)Related Product Information

• Sodium trifluoromethanesulfinate
• Trifluoromethanesulfonic acid
• TRIFLUOROMETHANESULFONIC ACID 6-BROMO-2-NAPHTHYL ESTER
• 1-(TRIMETHYLSILYL)-2-NAPHTHYL TRIFLATE
• 2-NAPHTHYL TRIFLATE
• (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)
• METHYL 2-TRIFLUOROMETHANESULFONYLOXY-1-NAPHTHOATE
• 3-(TRIMETHYLSILYL)-2-NAPHTHYL TRIFLUOROMETHANESULFONATE